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Synthesis of azolyl-substituted adamantane derivatives and their coordination compounds

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Abstract

Reactions of adamantylazoles with nucleophiles (water, carbon monoxide, acetonitrile) in sulfuric acid were studied. New bifunctional adamantane derivatives containing one heterocyclic substituent and one hydroxyl or acetamide substituent were synthesized. The coordination compounds of copper(II) and zinc(II) with 1-adamantyl-1,2,4-triazole, 4-adamantylpyrazole, and 4-adamantyl-3,5-dimethylpyrazole were synthesized and structurally characterized. These complexes are first examples of coordination compounds of azolyladamantanes.

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Authors and Affiliations

  1. National Research Tomsk Polytechnic University, 30 prosp. Lenina, 634050, Tomsk, Russian Federation

    D. I. Pavlov

  2. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, 3 prosp. Akad. Lavrentieva, 630090, Novosibirsk, Russian Federation

    T. S. Sukhikh & A. S. Potapov

  3. Novosibirsk State University, 1 ul. Pirogova, 630090, Novosibirsk, Russian Federation

    T. S. Sukhikh

Authors
  1. D. I. Pavlov
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  2. T. S. Sukhikh
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  3. A. S. Potapov
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Corresponding author

Correspondence to A. S. Potapov.

Additional information

The study was performed within the framework of the state assignment for the Nikolaev Institute of Inorganic Chemistry of the Siberian Branch of the Russian Academy of Sciences in the field of fundamental scientific research.

Russian Chemical Bulletin, International Edition, Vol. 69, No. 10, pp. 1953–1964, October, 2020

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 10, pp. 1953–1964, October, 2020.

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Pavlov, D.I., Sukhikh, T.S. & Potapov, A.S. Synthesis of azolyl-substituted adamantane derivatives and their coordination compounds. Russ Chem Bull 69, 1953–1964 (2020). https://doi.org/10.1007/s11172-020-2985-2

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  • DOI: https://doi.org/10.1007/s11172-020-2985-2

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