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Organochromiumoxane yttriumoxane alumoxane oligomers: synthesis, properties, pyrolysis

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Abstract

Ceramic-forming organochromiumoxane yttriumoxane alumoxane oligomers with a given molar ratio of Al: Cr and Al: Y, hydrolytically stable in air, have been synthesized. The materials demonstrate fiber-forming properties. It is established that thermal treatment of the obtained oligomers leads to the formation of high purity, heat-resistant multicomponent ceramics based on aluminum, yttrium and chromium oxides, in particular, alumina and garnet fibers modified with chromium oxides.

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Authors and Affiliations

  1. State Research Institute for Chemistry and Technology of Organoelement Compounds, 38 prosp. Entuziastov, 105118, Moscow, Russian Federation

    G. I. Shcherbakova, N. B. Kutinova, M. S. Varfolomeev, A. I. Drachev, M. G. Kuznetsova & P. A. Storozhenko

Authors
  1. G. I. Shcherbakova
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  2. N. B. Kutinova
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  3. M. S. Varfolomeev
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  4. A. I. Drachev
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  5. M. G. Kuznetsova
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  6. P. A. Storozhenko
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Corresponding author

Correspondence to G. I. Shcherbakova.

Additional information

Based on the materials of the XXI Mendeleev Congress on General and Applied Chemistry (September 9–13, 2019, St. Petersburg, Russia).

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 1492–1502, August, 2020.

This work was financially supported by the Russian Foundation for Basic Research (Project No. 17-03-00331 A).

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Shcherbakova, G.I., Kutinova, N.B., Varfolomeev, M.S. et al. Organochromiumoxane yttriumoxane alumoxane oligomers: synthesis, properties, pyrolysis. Russ Chem Bull 69, 1492–1502 (2020). https://doi.org/10.1007/s11172-020-2928-y

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  • DOI: https://doi.org/10.1007/s11172-020-2928-y

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