Abstract
Polymers based on methacrylic monomers were synthesized using 4,6-di-tert-butyl-N-(2,6-diisopropylphenyl)-o-iminobenzoquinone. They can be used for the directed synthesis of linear block copolymers with various compositions in the wide range of molecular weights under conditions of the polymerization according to the mechanism of reversible inhibition. It has been demonstrated that a structure of monomer plays the key role in the synthesis of block copolymers with relatively low values of the polydispersity coefficient. The optimal conditions for the synthesis of linear block copolymers based on methacrylic structures monomers have been revealed.
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References
K. Matyjaszewski, Eur. Polym. J., 2017, 89, 482.
J. F. Lutz, J. M. Lehn, E. W. Meyer, K. Matyjaszewski, Nat. Rev. Mat., 2016, 1, 16024.
C. Boyer, N. A. Corrigan, K. Jung, D. Nguyen, T. K. Nguyen, N. N. Adnan, S. Oliver, S. Shanmugam, J. Yeow, Chem. Rev., 2016, 116, 1803.
A. Anastasaki, V. Nikolaou, G. Nurumbetov, P. Wilson, K. Kempe, J. F. Quinn, T. P. Davis, M. R. Whittaker, D. M. Haddleton, Chem. Rev., 2016, 116, 835.
D. Braun, H. Cherdron, M. Rehahn, H. Ritter, B. Voit, Polymer Synthesis: Theory and Practice Fundamentals, Methods, Experiments, Springer, 2013, 404 pp.
E. V. Kolyakina, D. F. Grishin, Russ. Chem. Rev., 2011, 80, 683.
O. S. Lizyakina, L. B. Vaganova, M. G. Chegerev, A. V. Piskunov, D. F. Grishin, Polymer Sci., Ser. B (Engl. Transl.), 2019, 61, 132.
L. B. Vaganova, O. S. Lizyakina, M. G. Chegerev, A. V. Piskunov, D. F. Grishin, Polymer Sci., Ser. B (Engl. Transl.), 2017, 59, 506.
L. A. Utracki, C. A. Wilkie, Polymer Blends Handbook, Springer, New York—Heidelberg—Dordrecht—London, 2003, 2375 p.
Entsiklopedia polimerov [Encyclopedia of Polymers] Sov. Entsiklopedia, Moscow, 1972, 1, p. 1224 (in Russian).
Organic Synthesis. An Annual Publication of Satisfactory Methods for the Preparation of Organic Chemicals, Wiley & Sons, New York, 1953.
A. J. Gordon, R. A. Ford, The Chemist’s Companion: A Handbook of Practical Data, Techniques, and References, Wiley & Sons, New York, 1973, 560.
G. A. Abakumov, N. O. Druzhkov, Yu. A. Kurskii, A. S. Shavyrin, Russ. Chem. Bull., 2003, 52, 712.
B. G. Belen’kiy, L. Z. Vilenchik, Khromatografia polimerov [Chromatography of Polymers], Khimia, Moscow, 1978, 344 pp. (in Russian).
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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 1478–1485, August, 2020.
The authors are grateful to I. D. Grishin for the registration and interpretation of MALDI-TOF spectra.
This work was carried out within the framework of State Assignment of the Ministry of Science and Higher Education of the Russian Federation (Project Code 4.5706.2017/BCh) and financially supported in parts by the Russian Foundation for Basic Research (Project No. 20-03-00150).
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Lizyakina, O.S., Vaganova, L.B., Piskunov, A.V. et al. Synthesis of linear block copolymers from methacrylic monomers using 4,6-di-tert-butyl-N-2,6-diisopropylphenyl)-o-iminobenzoquinone. Russ Chem Bull 69, 1478–1485 (2020). https://doi.org/10.1007/s11172-020-2926-0
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DOI: https://doi.org/10.1007/s11172-020-2926-0