Abstract
The effect of pH on the zeta potential of dispersions of individual n-alkanes C23H48 and C28H58 with particle sizes of the order of 100 nm, which were prepared by ultrasonic dispersion without the addition of surfactants, was studied. It is shown that at pH ranged from 4 to 12, the investigated n-alkanes form stable dispersions in water. They are characterized by a high zeta potential varying from −30 to −50 mV. The phase transition temperatures (melting point, crystallization temperature, formation of rotator phases) were determined for the dispersions using an optical method.
Similar content being viewed by others
References
S. Amselem, D. Friedman, in Submicron Emulsions in Drug Targeting and Delivery, Ed. S. Benita, Hardwood Academic Publ., Amsterdam, 1998, p. 153.
M. Yu. Koroleva, E. V. Yurtov, Russ. Chem. Rev., 2012, 81, 21.
K. Du, J. Calautit, Z. Wang, Y. Wu, H. Liu, Appl. Energy, 2018, 220, 242.
S. Kahwaji, M. B. Johnson, A. C. Kheirabadi, D. Groulx, M. A. White, Energy, 2018, 162, 1169.
H. Akeiber, P. Nejat, M. Z. A. Majid, M. A. Wahid, F. Jomehzadeh, I. Z. Famileh, J. K. Calautit, B. R. Hughes, S. A. Zaki, Renew. Sust. Energy Rev., 2016, 60, 1470.
Z. Youssef, A. Delahaye, L. Huang, F. Trinquet, L. Fournaison, C. Pollerberg, C. Doetsch, Energy Convers. Manag., 2013, 65, 120.
D. D. Ivanova, K. I. Kienskaya, V. N. Kuryakov, Uspekhi v Khimii i Khim. Technol. [Adv. Chem. Chem. Technol.], 2018, 32, No. 7(203), 15 (in Russian).
D. D. Ivanova, K. I. Kienskaya, V. N. Kuryakov, Uspekhi v Khimii i Khim. Technol. [Adv. Chem. Chem. Technol.], 2017, 31, No. 4(185), 88 (in Russian).
V. N. Kuryakov, P. G. De Sanctis Lucentini, D. D. Ivanova, IOP Conf. Ser.: Mater. Sci. Eng., 2018, 347, 012034; DOI: https://doi.org/10.1088/1757-899X/347/1/012034.
V. N. Kuryakov, D. D. Ivanova, Int. J. Nanosci., 2019, 18, 1940032.
A. Wessler, J. Am. Chem. Soc., 1959, 81, 1077.
T. P. Klokova, Yu. A. Volodin, O. F. Glagoleva, Chem. Technol. Fuels Oils, 2006, 42, 43.
E. B. Sirota, H. E. King, D. M. Singer, H. H. Shao, J. Chem. Phys., 1993, 98, 5809.
E. B. Sirota, D. M. Singer, J. Chem. Phys., 1994, 101, 10873.
J. F. Johnson, Ind. Eng. Chem., 1954, 46, 1046.
H. Kraack, E. B. Sirota, M. Deutsch, J. Chem. Phys., 2000, 112, 6873.
D. Turnbull, R. L. Cormia, J. Chem. Phys., 1961, 34, 820.
Author information
Authors and Affiliations
Corresponding author
Additional information
Based on the materials of the XXI Mendeleev Congress on General and Applied Chemistry (September 9–13, 2019, St. Petersburg, Russia).
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 7, pp. 1306–1310, July, 2020.
Rights and permissions
About this article
Cite this article
Kuryakov, V.N., Ivanova, D.D. & Kienskaya, K.I. Study of the physicochemical characteristics of dispersions of n-alkanes C23H48 and C28H58 in water: zeta potential and temperatures of phase transitions. Russ Chem Bull 69, 1306–1310 (2020). https://doi.org/10.1007/s11172-020-2902-8
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11172-020-2902-8