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Electroplating of zinc and tin alloys with nickel and cobalt from ammonium oxalate electrolytes

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Abstract

A possibility of preparing good quality electrolytic alloys zinc-nickel, zinc-cobalt, tin-nickel, and tin-cobalt from ammonium oxalate electrolytes of various compositions was shown. The alloy coatings of high quality can be obtained at the current density range from 1 to 3 A dm−2. The introduction into the electrolyte of ammonium oxalate capable of forming stable complexes with Zn2+, Sn2+, Ni2+, and Co2+ ions makes it possible to increase the working pH range. Electroplating occurs with high cathodic polarization favoring the formation of qualitative finely crystalline coatings of the plated alloys.

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Authors and Affiliations

  1. Ivanovo State University of Chemistry and Technology, 7 Sheremetevsky prosp., 153000, Ivanovo, Russian Federation

    K. A. Kamysheva, R. F. Shekhanov, S. N. Gridchin & A. V. Balmasov

Authors
  1. K. A. Kamysheva
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  2. R. F. Shekhanov
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  3. S. N. Gridchin
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  4. A. V. Balmasov
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Corresponding author

Correspondence to R. F. Shekhanov.

Additional information

Based on the materials of the XXI Mendeleev Congress on General and Applied Chemistry (September 9–13, 2019, St. Petersburg, Russia).

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 7, pp. 1272–1278, July, 2020.

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Kamysheva, K.A., Shekhanov, R.F., Gridchin, S.N. et al. Electroplating of zinc and tin alloys with nickel and cobalt from ammonium oxalate electrolytes. Russ Chem Bull 69, 1272–1278 (2020). https://doi.org/10.1007/s11172-020-2897-1

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  • DOI: https://doi.org/10.1007/s11172-020-2897-1

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