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Modification of the hypercrosslinked polystyrene surface. New approaches to the synthesis of polymer-stabilized catalysts

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Abstract

The structure and activity of novel combined ruthenium-containing catalysts based on hypercrosslinked polystyrene modified with Fe3O4 and SiO2 were studied. The modification of the polymeric support surface aimed at imparting new properties to the catalysts is a prospective approach for the development of highly efficient catalytic systems involved in various processes. The synthesized samples are characterized by a high specific surface area and a high catalytic activity in the liquid-phase Fischer—Tropsch synthesis providing a yield of liquid hydrocarbons C6-C12 up to 82%.

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References

  1. B. M. L. Dioos, I. F. J. Vankekecom, P. A. Jacobs, Adv. Synth. Catal., 2006, 348, 1413.

    CAS  Google Scholar 

  2. D. E. Bergbreiter, Chem. Rev., 2002, 102, 3345.

    CAS  PubMed  Google Scholar 

  3. T. J. Dikerson, N. N. Reed, K. D. Janda, Chem. Rev., 2002, 102, 3325.

    Google Scholar 

  4. D. E. Bergbreiter, S. D. Sung, Adv. Synth. Catal., 2006, 348, 1352.

    CAS  Google Scholar 

  5. D. E. Bergbreiter, J. Tian, C. Hongfa, Chem. Rev., 2009, 109, 530.

    CAS  PubMed  Google Scholar 

  6. H. P. Dijkstra, G. P. M. Van Klink, G. Van Koten, Acc. Chem. Res., 2002, 35, 798.

    PubMed  Google Scholar 

  7. W. D. Bonds, C. H. Brubaker, E. S. Chandrasekaran, C. Gibbons, K. H. Grubbs, L. C. Kroll, J. Am. Chem. Soc., 1975, 97, 2128.

    CAS  Google Scholar 

  8. C. U. Pittman, J. C. Lai, D. P. Vanderpool, M. Good, R. Prado, Macromolecules, 1970, 3, 746.

    CAS  Google Scholar 

  9. C. G. Frost, L. Mutton, Green Chem., 2010, 12, 1687.

    CAS  Google Scholar 

  10. L. Tan, B. Tan, Chem. Soc. Rev., 2017, 46, 3322.

    CAS  PubMed  Google Scholar 

  11. J. Huang, S. R. Turner, Polym. Rev., 2017, 1.

  12. R. Dawson, A. I. Cooper, D. J. Adams, Polym. Int., 2013, 62, 345.

    CAS  Google Scholar 

  13. R. Dawson, L. A. Stevens, T. C. Drage, C. E. Snape, M. W. Smith, D. J. Adams, A. I. Cooper, J. Am. Chem. Soc., 2012, 134, 10741.

    CAS  PubMed  Google Scholar 

  14. J. Germain, F. Svec, J. M. J. Fréchet, Chem. Mater., 2008, 20, 7069.

    CAS  Google Scholar 

  15. R. T. Woodward, L. A. Stevens, R. Dawson, M. Vijayaraghavan, T. Hasell, I. P. Silverwood, A. V. Ewing, T. Ratvijitvech, J. D. Exley, S. Y. Chong, J. Am. Chem. Soc., 2014, 136, 9028.

    CAS  PubMed  Google Scholar 

  16. S. E. Lyubimov, L. A. Pavlova, M. V. Sokolovskaya, A. A. Korlyukov, V. A. Davankov, Russ. Chem. Bull., 2019, 68, 1599.

    CAS  Google Scholar 

  17. Author’s Certificate 948110 USSR; Byul. Izobret. [Invention Bulletin], 1983, 15 (in Russian).

  18. P. Veverka, K. Jerábek, React. Funct. Polym., 1999, 41, 21.

    CAS  Google Scholar 

  19. J. H. Ahn, J. E. Jang, C. G. Oh, S. K. Ihm, J. Cortez, D. C. Sherrington, Macromolecules, 2006, 39, 627.

    CAS  Google Scholar 

  20. S. Lowell, J. E. Shields, M. A. Thomas, M. Thommes, in Characterization of Porous Solids and Powders: Surface Area, Pore Size and Density, Kluwer Academic Publishers, Dordrecht, 2004, p. 152.

    Google Scholar 

  21. S. N. Sidorov, L. M. Bronstein, V. A. Davankov, M. P. Tsyurupa, S. P. Solodovnikov, P. M. Valetsky, E. A. Wilder, R. J. Spontak, Chem. Mater., 1999, 11, 3210.

    CAS  Google Scholar 

  22. S. N. Sidorov, I. V. Volkov, V. A. Davankov, M. P. Tsyurupa, P. M. Valetsky, L. M. Bronstein, R. Karlinsey, J. W. Zwanziger, V. G. Matveeva, E. M. Sulman, N. V. Lakina, E. A. Wilder, R. J. Spontak, J. Am. Chem. Soc., 2001, 123, 10502.

    CAS  PubMed  Google Scholar 

  23. L. M. Bronstein, G. Goerigk, M. Kostylev, M. Pink, I. A. Khotina, P. M. Valetsky, V. G. Matveeva, E. M. Sulman, M. G. Sulman, A. V. Bykov, N. V. Lakina, R. J. Spontak, J. Phys. Chem. B., 2004, 108, 18234.

    CAS  Google Scholar 

  24. A. Bykov, V. Matveeva, M. Sulman, P. Valetsky, O. Tkachenko, L. Kustov, L. Bronstein, E. Sulman, Catal. Today, 2009, 140, 64.

    CAS  Google Scholar 

  25. V. Y. Doluda, E. M. Sulman, V. G. Matveeva, M. G. Sulman, N. V. Lakina, A. I. Sidorov, P. M. Valetsky, L. M. Bronstein, Chem. Eng. J., 2007, 134, 256.

    CAS  Google Scholar 

  26. E. M. Sulman, V. G. Matveeva, V. Y. Doluda, A. I. Sidorov, N. V. Lakina, A. V. Bykov, M. G. Sulman, P. M. Valetsky, L. M. Kustov, O. P. Tkachenko, B. D. Stein, L. M. Bronstein, Appl. Catal. B., 2010, 94, 200.

    CAS  Google Scholar 

  27. I. B. Tsvetkova, V. G. Matveeva, V. Y. Doluda, A. V. Bykov, A. I. Sidorov, S. V. Schennikov, M. G. Sulman, P. M. Valetsky, B. D. Stein, C.-H. Chen, E. M. Sulman, L. M. Bronstein, J. Mater. Chem., 2012, 22, 6441.

    CAS  Google Scholar 

  28. L. Nikoshvili, E. Shimanskaya, A. Bykov, I. Yuranov, L. Kiwi-Minsker, E. Sulman, Catal. Today, 2015, 241, 179.

    CAS  Google Scholar 

  29. V. N. Sapunov, A. A. Stepacheva, E. M. Sulman, J. Wärnå, P. Mäki-Arvela, M. G. Sulman, A. I. Sidorov, B. D. Stein, D. Y. Murzin, V. G. Matveeva, J. Ind. Eng. Chem., 2017, 46, 426.

    CAS  Google Scholar 

  30. E. Sulman, V. Doluda, S. Dzwigaj, E. Marceau, L. Kustov, O. Tkachenko, A. Bykov, V. Matveeva, M. Sulman, N. Lakina, J. Mol. Catal. A: Chem., 2007, 278, 112.

    CAS  Google Scholar 

  31. I. I. Protsenko, L. Z. Nikoshvili, A. V. Bykov, V. G. Matveeva, A. M. Sulman, E. M. Sulman, E. V. Rebrov, Green Process. Synth., 2017, 6, 281.

    CAS  Google Scholar 

  32. V. N. Sapunov, M. Y. Grigoryev, E. M. Sulman, M. B. Konyaeva, V. G. Matveeva, J. Phys. Chem. A., 2013, 117, 4073.

    CAS  PubMed  Google Scholar 

  33. E. M. Sulman, V. G. Matveeva, O. V. Manaenkov, A. E. Filatova, O. V. Kislitza, V. Y. Doluda, E. V. Rebrov, A. I. Sidorov, E. I. Shimanskaya, AIP Conf. Proc., 2016, 1787, 30004.

    Google Scholar 

  34. A. I. Sidorov, O. P. Tkachenko, E. M. Sulman, V. Y. Doluda, A. A. Stepacheva, Chem. Eng. Trans., 2017, 61, 607.

    Google Scholar 

  35. A. Malinovsky, V. Matveeva, E. Sulman, V. Doluda, A. Stepacheva, E. Rebrov, Chem. Eng. Trans., 2017, 61, 613.

    Google Scholar 

  36. A. A. Stepacheva, M. E. Markova, A. V. Bykov, A. I. Sidorov, M. G. Sulman, V. G. Matveeva, E. M. Sulman, Reac. Kinet. Mech. Cat., 2018, 125, 213.

    CAS  Google Scholar 

  37. A. A. Stepacheva, A. I. Sidorov, V. G. Matveeva, M. G. Sulman, E. M. Sulman, Chem. Eng. Technol., 2019, 42, 780.

    CAS  Google Scholar 

  38. R. Vasita, K. I. Shanmugam, D. S. Katt, Curr. Top. Med. Chem., 2008, 8, 341.

    CAS  PubMed  Google Scholar 

  39. R. Castaldo, R. Avolio, M. Cocca, G. Gentile, M. E. Errico, M. Avella, C. Carfagna, V. Ambrogi, RSC Adv., 2017, 7, 6865.

    CAS  Google Scholar 

  40. R. Castaldo, R. Avolio, M. Cocca, G. Gentile, M. E. Errico, M. Avella, C. Carfagna, V. Ambrogi, Macromolecules, 2017, 50, 4132.

    CAS  Google Scholar 

  41. H. Jahangiri, J. Bennett, P. Mahjoubi, K. Wilson, S. Gu, Catal. Sci. Technol., 2014, 4, 2210.

    CAS  Google Scholar 

  42. J.-H. Oh, J. W. Bae, S.-J. Park, P. K. Khanna, K.-W. Jun, Catal. Lett., 2009, 130, 403.

    CAS  Google Scholar 

  43. M. E. Markova, A. V. Gavrilenko, A. A. Stepacheva, V. P. Molchanov, V. G. Matveeva, M. G. Sulman, E. M. Sulman, Kinet. Catal., 2019, 60, 618.

    CAS  Google Scholar 

  44. M. Thommes, K. Kaneko, A. V. Neimark, J. P. Olivier, F. Rodrigues-Reinoso, J. Rouquerol, K. W. Sing, Pure Appl. Chem., 2015, 87, 1051.

    CAS  Google Scholar 

  45. A. P. Grosvenor, B. A. Kobe, M. C. Biesinger, N. S. McIntyre, Surf. Interface Anal., 2004, 36, 1564.

    CAS  Google Scholar 

  46. T. Radu, C. Iacovita, D. Benea, R. Turcu, Appl. Surf. Sci., 2017, 405, 337.

    CAS  Google Scholar 

  47. D. J. Morgan, Surf. Interface Anal., 2015, 47, 1072.

    CAS  Google Scholar 

  48. M. Ahmadzadeh, C. Romero, J. McCloy, AIP Adv., 2008, 8, 056807.

    Google Scholar 

  49. R. Ghita, C. Logofatu, C.-C. Negrila, F. Ungureanu, C. Co-tirlan, A.-S. Manea, M.-F. Lazarescu, C. Ghica, in Crystalline Silicon — Properties and Uses, Ed. S. Basu, InTech, Croatia, 2011, p. 344.

  50. M. E. Bartram, T. A. Michalske, J. W. Rogers Jr., T. M. Mayer, Chem. Mater., 1991, 3, 953.

    CAS  Google Scholar 

  51. C. Xing, J. Sun, Q. Chen, G. Yang, N. Muranaka, P. Lu, W. Shen, P. Zhu, J. Li, J. Mao, R. Yang, N. Tsubaki, Catal. Today, 2015, 251, 41.

    CAS  Google Scholar 

  52. K. Cheng, M. Virginie, V. V. Ordomsky, C. Cordier, P. A. Chernavskii, M. I. Ivantsov, S. Paul, Y. Wang, A. Y. Khoda-kov, J. Catal., 2015, 328, 139.

    CAS  Google Scholar 

  53. S. Li, S. Krishnamoorthy, A. Li, G. D. Meitzner, E. Iglesia, J. Catal., 2002, 206, 202.

    CAS  Google Scholar 

  54. W. Ma, G. Jacobs, T. K. Das, C. Mduduzi Masuku, J. Kang, V. R. Rao Pendyala, B. H. Davis, Ind. Eng. Chem. Res., 2014, 53, 2157.

    CAS  Google Scholar 

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Authors and Affiliations

  1. Tver State Technical University, 22 nab. A. Nikitina, 170026, Tver, Russian Federation

    A. A. Stepacheva, M. E. Markova, O. V. Manaenkov, A. V. Gavrilenko, A. I. Sidorov, M. G. Sulman, Yu. Yu. Kosivtsov, V. G. Matveeva & E. M. Sulman

  2. Tver State University, 33 ul. Zhelyabova, 170100, Tver, Russian Federation

    M. E. Markova & V. G. Matveeva

Authors
  1. A. A. Stepacheva
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  2. M. E. Markova
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  3. O. V. Manaenkov
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  4. A. V. Gavrilenko
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  5. A. I. Sidorov
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  6. M. G. Sulman
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  7. Yu. Yu. Kosivtsov
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  8. V. G. Matveeva
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  9. E. M. Sulman
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Correspondence to A. A. Stepacheva.

Additional information

This work was financially supported by the Russian Foundation for Basic Research (Project Nos 18-29-06004 and 18-08-00404).

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 4, pp. 0721–0730, April, 2020.

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Stepacheva, A.A., Markova, M.E., Manaenkov, O.V. et al. Modification of the hypercrosslinked polystyrene surface. New approaches to the synthesis of polymer-stabilized catalysts. Russ Chem Bull 69, 721–730 (2020). https://doi.org/10.1007/s11172-020-2824-5

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  • DOI: https://doi.org/10.1007/s11172-020-2824-5

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