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One-dimensional magnet basic copper(ii) dihydroxoborate Cu2{BO(OH)2}(OH)3: synthesis and properties

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Abstract

Basic copper(ii) dihydroxoborate Cu2{BO(OH)2}(OH)3 contains infinite chains consisting of [CuO4] squares that are linked together by sharing opposite edges, due to which this compound is interesting in terms of low-dimensional magnetism. However, investigations of its physical properties are hindered by difficulties with the preparation of single-phase samples. The synthesis method was optimized, and the factors affecting the formation of a crystalline product were established. The synthesized compound was characterized by X-ray diffraction and IR spectroscopy, and its thermal stability was studied. The crystallite formation from the initially unstructured precipitate is described using scanning electron microscopy. An investigation of the temperature dependence of magnetic susceptibility showed that the magnetic properties of basic copper(ii) borate are well described by the weakly alternating spin-1/2 Heisenberg chain model.

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Authors and Affiliations

  1. Department of Chemistry, Lomonosov Moscow State University, Build. 3, 1 Leninskie Gory, 119991, Moscow, Russian Federation

    A. A. Vorobyova, A. I. Shilov, F. M. Spiridonov, A. V. Knotko & I. V. Morozov

  2. V. L. Ginzburg Center for High-Temperature Superconductivity and Quantum Materials, P. N. Lebedev Physical Institute, Russian Academy of Sciences, 53 Leninsky prosp., 119991, Moscow, Russian Federation

    A. I. Shilov

  3. Department of Physics, Lomonosov Moscow State University, Build. 2, 1 Leninskie Gory, 119991, Moscow, Russian Federation

    I. L. Danilovich & A. N. Vasiliev

Authors
  1. A. A. Vorobyova
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  2. A. I. Shilov
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  3. F. M. Spiridonov
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  4. A. V. Knotko
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  5. I. L. Danilovich
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  6. A. N. Vasiliev
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  7. I. V. Morozov
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Corresponding authors

Correspondence to A. A. Vorobyova or I. V. Morozov.

Additional information

We thank P. P. Fedorov for helpful discussion.

This work was financially supported by the Russian Foundation for Basic Research (Project No.19-03-01059-A).

Based on the materials of the 5th EuChemS Inorganic Chemistry Conference (EICC-5, June 24–28, 2019, Moscow, Russia).

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 4, pp. 0704–0711, April, 2020.

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Vorobyova, A.A., Shilov, A.I., Spiridonov, F.M. et al. One-dimensional magnet basic copper(ii) dihydroxoborate Cu2{BO(OH)2}(OH)3: synthesis and properties. Russ Chem Bull 69, 704–711 (2020). https://doi.org/10.1007/s11172-020-2821-8

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  • DOI: https://doi.org/10.1007/s11172-020-2821-8

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