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Nickel(ii) N-heterocyclic carbene complexes as efficient catalysts for the Suzuki—Miyaura reaction

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Abstract

Catalytic activity of nickel(ii) and palladium(ii) N-heterocyclic carbene (NHC) complexes derived from imidazole, benzimidazole, and 1,2,4-triazole was comparatively evaluated in the cross-coupling reactions of aryl halides with arylboronic acids. Readily available nickel bis-NHC complexes (NHC)2NiX2 (X = Cl, Br, or I) exhibited the activity comparable to that of the structurally related palladium complexes and, consequently, can be applied as efficient catalysts for the Suzuki—Miyaura reaction.

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Authors and Affiliations

  1. M. I. Platov South-Russian State Polytechnic University (NPI), 132 ul. Prosveshcheniya, 346428, Novocherkassk, Russian Federation

    S. B. Soliev, A. V. Astakhov, D. V. Pasyukov & V. M. Chernyshev

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  1. S. B. Soliev
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  2. A. V. Astakhov
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  3. D. V. Pasyukov
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  4. V. M. Chernyshev
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Corresponding author

Correspondence to V. M. Chernyshev.

Additional information

The authors are grateful to Academician of the Russian Academy of Sciences V. P. Ananikov for the fruitful discussion of the results and valuable comments. The authors are also grateful to the Shared Research Center “Nanotech nologies” of the M. I. Platov South-Russian State Polytechnic University (NPI) and the Department of Structural Studies of the N. D. Zelinsky Institute of Organic Chemistry of the Russian Academy of Sciences for carrying out the analytical experiments.

This work was financially supported by the Russian Foundation for Basic Research (Project No. 16-29-10786).

Based on the materials of the International Conference “Catalysis and Organic Synthesis” (ICCOS-2019) (September 15–20, 2019, Moscow, Russia).

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 4, pp. 0683–0690, April, 2020.

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Soliev, S.B., Astakhov, A.V., Pasyukov, D.V. et al. Nickel(ii) N-heterocyclic carbene complexes as efficient catalysts for the Suzuki—Miyaura reaction. Russ Chem Bull 69, 683–690 (2020). https://doi.org/10.1007/s11172-020-2818-3

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  • DOI: https://doi.org/10.1007/s11172-020-2818-3

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