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Phase equilibria and structures of phases in the chitosan—polyvinyl alcohol systems

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Abstract

Phase equilibria in the mixtures of polyvinyl alcohol (PVA) and chitosan were revealed. Structures of the phases were identified. The temperature and concentration dependences for the chitosan—PVA and chitosan—PVA—water systems were determined. The phase state diagram was built. It is shown that the polymer mixtures are characterized by a complex supramolecular organization, which corresponds to their phase diagram.

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Authors and Affiliations

  1. A. N. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, 31 Build., 4 Leninsky prosp., 119072, Moscow, Russian Federation

    A. E. Chalykh, T. F. Petrova, V. V. Matveev, V. K. Gerasimov, R. R. Khasbiullin, A. A. Shcherbina & N. A. Abaturova

  2. D. Mendeleev University of Chemical Technology of Russia, 9 Miusskaya pl., 125047, Moscow, Russian Federation

    A. A. Shcherbina

Authors
  1. A. E. Chalykh
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  2. T. F. Petrova
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  3. V. V. Matveev
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  4. V. K. Gerasimov
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  5. R. R. Khasbiullin
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  6. A. A. Shcherbina
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  7. N. A. Abaturova
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Corresponding author

Correspondence to T. F. Petrova.

Additional information

This work was performed within the framework of the state task of the Ministry of Education and Science of the Russian Federation (Project No. AAAA-A19-119011790097-9 dated 01.17.2019).

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 4, pp. 0675–0682, April, 2020.

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Chalykh, A.E., Petrova, T.F., Matveev, V.V. et al. Phase equilibria and structures of phases in the chitosan—polyvinyl alcohol systems. Russ Chem Bull 69, 675–682 (2020). https://doi.org/10.1007/s11172-020-2817-4

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  • DOI: https://doi.org/10.1007/s11172-020-2817-4

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