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Structural features of composite protein-polysaccharide hydrogel in the presence of a carbon nanomaterial

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Abstract

The structures of a protein-polysaccharide composite hydrogel and its modifications prepared using carbon nanotubes (CNTs) were studied by small-angle X-ray scattering and scanning electron microscopy. A correlation between the morphology and physicochemical properties of the hydrogels is demonstrated taking the specific electrical conductivity of the hydrogels as an example. It is shown that the specific electrical conductivity is unambiguously related to the structure of the systems studied, viz., the higher the density of cross-links between biopolymer chains the lower the conductivity, and vice versa. It is found that the addition of CNTs to K-carrageenan—gelatin composite hydrogels can lead to either increase or decrease in their electrical conductivity.

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Authors and Affiliations

  1. Kazan State Power Engineering University, 51 ul. Krasnoselskaya, 420066, Kazan, Russian Federation

    O. S. Zueva

  2. A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences, 8 ul. Akad. Arbuzova, 420088, Kazan, Russian Federation

    A. T. Gubaidullin & L. Ya. Zakharova

  3. Kazan Institute of Biochemistry and Biophysics, Kazan Scientific Center of the Russian Academy of Sciences, 2/31 ul. lobachevskogo, 420111, Kazan, Russian Federation

    A. O. Makarova, L. R. Bogdanova & Yu. F. Zuev

Authors
  1. O. S. Zueva
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  2. A. T. Gubaidullin
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  3. A. O. Makarova
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  4. L. R. Bogdanova
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  5. L. Ya. Zakharova
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  6. Yu. F. Zuev
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Corresponding author

Correspondence to Yu. F. Zuev.

Additional information

X-Ray studies (A. T. Gubaidullin) were carried out at the Spectro-Analytical Center of Collective Use at the Kazan Scientific Center of the Russian Academy of Sciences (facilities at the Laboratory of Diffraction Methods of Investigation).

This work was carried out within the framework of the State Assignment to the Kazan Scientific Center of the Russian Academy of Sciences (A. T. Gubaidullin, L. R. Bogdanova, L. Ya. Zakharova, Yu. F. Zuev — general analysis of the results obtained). It was financially supported in part by the Russian Foundation for Basic Research (Project No. 19-38-90085; A. O. Makarova — conductometry) and by the Russian Foundation for Basic Research and the Government of the Republic of Tatarstan within the framework of the Joint Project No. 18-415-160011 (L. R. Bogdanova, Yu. F. Zuev — SEM experiments).

Based on the materials of the International Markovnikov Congress on Organic Chemistry (June 21–28, 2019, Moscow-Kazan, Russia).

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 3, pp. 0581—0589, March, 2020.

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Zueva, O.S., Gubaidullin, A.T., Makarova, A.O. et al. Structural features of composite protein-polysaccharide hydrogel in the presence of a carbon nanomaterial. Russ Chem Bull 69, 581–589 (2020). https://doi.org/10.1007/s11172-020-2802-y

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  • DOI: https://doi.org/10.1007/s11172-020-2802-y

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