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Transesterification of dialkyl carbonates by poly(4-vinylphenol)

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Abstract

Transesterification of dialkyl carbonates and fluorine-containing carbonates by poly(4-vinyl-phenol) was studied in order to develop the method for synthesis of polymers containing a carbonate functional group in the side chain. The compositions of the obtained products were characterized by the data of elemental analysis, IR spectroscopy, and thermogravimetry with identification of the decomposition products. Cross-linking of the polymer occurs along with transesterification. The degree of functionalization depends on the composition of the carbonate used. The maximum conversion was achieved when using ethyl 2,2,3,3-tetrafluoropropyl carbonate.

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Authors and Affiliations

  1. I. Ya. Postovskii Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences, 22/20 ul. S. Kovalevskoi, 620137, Yekaterinburg, Russian Federation

    A. M. Semenova, E. F. Zhilina, A. V. Mekhaev, A. Ya. Zapevalov & A. V. Pestov

  2. Ural Federal University named after First President of Russia B. N. Yeltsin, 19 ul. Mira, 620002, Yekaterinburg, Russian Federation

    A. V. Pestov

Authors
  1. A. M. Semenova
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  2. E. F. Zhilina
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  3. A. V. Mekhaev
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  4. A. Ya. Zapevalov
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  5. A. V. Pestov
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Corresponding author

Correspondence to A. V. Pestov.

Additional information

Based on the materials of the V International Scientific Conference “Advances in Synthesis and Complexing” (April 22-26, 2019, Moscow, Russia).

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 2, pp. 0265–0269, February, 2020

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Semenova, A.M., Zhilina, E.F., Mekhaev, A.V. et al. Transesterification of dialkyl carbonates by poly(4-vinylphenol). Russ Chem Bull 69, 265–269 (2020). https://doi.org/10.1007/s11172-020-2755-1

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  • DOI: https://doi.org/10.1007/s11172-020-2755-1

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