Abstract
Frequency measurements of aqueous solutions of dimethyl sulfoxide (DMSO) were carried out in the range of 0.5-36.5 GHz at temperatures 293-323 K. Relaxation spectra were used to determine dipole relaxation times and the distribution parameter of these times, which were in good agreement with the Cole-Cole model. The thermodynamic characteristics of dipole relaxation and viscous flow were calculated based on the obtained results and found to be similar to the energy characteristics of the hydrogen bond and to have maximum values in the region of 0.3-0.4 mole fractions of DMSO. Kinetics of intermolecular interaction suggesting the formation in mixtures of 1 ∶ 2 and 2 ∶ 1 DMSO-Н2О complexes were studied.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
Yu. N. Kukushkin, Soros. Obrazov. Zhurn. [Soros Edu. J.], 1997, No. 9, 54–59 (in Russian).
E. S. Verstakov, Ph. D. Thesis (Phys.-Math.), N. K. Krupskaya, Moscow Region Pedagogical Institute, Moscow, 1975, 116 pp. (in Russian).
Biological Actions of Dimethyl Sulfoxide, Ed. C. D. Leake, New York Academy of Science, New York, 1967.
S. W. Jacob, R. Herschler, Analls NY Acad. Sci., 1975, 243, 5–508.
J. M. G. Cowie, P. M. Toporowski, Can. J. Chem., 1961, 39, 2240–2243.
A. Luzar, J. Mol. Liq., 1990, 46, 221–238.
K. A. Akmarov, Ph. D. Thesis (Tech.), St.-Petersburg National Research University of Information Technologies and Optics, Saint Petersburg, 2013, 104 pp. (in Russian).
I. Plowas, J. Swiergiel, J. Jadzyn, J. Chem. Engineer., 2013, A-F.
U. Kaatze, R. Potter, M. Scliafer, J. Phys. Chem., 1989, 93, 5623–5627.
Li-Jun Yang, Xiao-Oing Yang, Ka-Ma Huang, Guo-Zhin Jia, Hui Shang, Int. J. Mol. Sci., 2009, 10, 1261–1270.
A. A. Brandt, Issledovanie dielektrikov na sverkhvysokikh chastotakh [Study of Dielectrics at Microwave Frequencies], Fizmatlit, Moscow, 1963, 404 pp. (in Russian).
S. Havriliak, S. Negami, J. Polym. Sci.: Part C., 1966, 99–117.
P. Debye, Polar Molecules, Chemical Catalog. Co, New York, USA, 1929.
D. W. Davidson, R. H. Cole, J. Chem. Phys., 1950, 18, 1417.
K. S. Cole, R. H. Cole, J. Chem. Phys., 1941, 9, 341–351.
H. Fröhlich, Theory of Dielectrics. Dielectric Constant and Dielectric Loss, 2nd ed., Clarendon Press, Oxford, 1958.
Z. Lu, E. Manias, M. Lanagan, D. D. Macdonald, ECS Trans., 2010, 28, No. 18, 11–21.
Z. S. Klemenkova, T. A. Novskova, A. K. Lyashchenko, Zh. Fiz. Khim., 2008, 82, 668–673 [Russ. J. Phys. Chem. (Engl. Transl.), 2008, 82] (in Russian).
S. Glasston, K. J. Laidler, H. Eyring, The Theory of Rate Processes. The Kinetics of Chemical Reactions, Viscosity, Dif usion and Electrochemical Phenomena, 1st ed., Second Impression, New York-London, 1941.
J. Kenttamaa, J. J. Zindberg, Suomen Kenistill, 1960, 33, 32.
D. B. Wong, K. P. Sokolowsky, M. I. El-Barghouthi, E. E. Fenn, Ch. H. Giammanco, A. L. Sturlaugson, M. D. Fayer, J. Phys. Chem. B, 2012, 116, 5479–5490.
I. A. Borin, M. S. Skaf, J. Chem. Phys., 1999, 110, 6412–6420.
B. Z. Gorbunov, Yu. N. Naberukhin, V. E. Slivkin, Zh. Struktur. Khim., 1974, 15, 403 [J. Struct. Chem. (USSR) (Engl. Transl.), 1974, 15] (in Russian).
Author information
Authors and Affiliations
Corresponding author
Additional information
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 2, pp. 0255–0259, February, 2020.
Rights and permissions
About this article
Cite this article
Verstakov, E.S., Korobkova, S.A. & Nosaeva, T.A. Dielectric spectrum and structure of aqueous solutions of dimethyl sulfoxide. Russ Chem Bull 69, 255–259 (2020). https://doi.org/10.1007/s11172-020-2753-3
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11172-020-2753-3