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Synthesis of double ammonium’calcium pyrophosphate monohydrate Ca(NH4)2P2O7•H2O as the p recursor of biocompatible phases of calcium phosphate ceramics

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Abstract

Double calcium’ammonium pyrophosphate monohydrate Ca(NH4)2P2O7•H2O was synthesized as a result of the interaction of calcium carbonate, an aqueous solution containing pyrophosphoric and lactic acids, and ammonia. The synthesized powder turned black after the thermal treatment in a range of 500—700 °C due to amorphous carbon, which is a product of the destruction of the organic nature components present in the prepared powder. After the thermal treatment at 500 °C, the powder is amorphous to X-rays. The phase composition of the powder after the thermal treatment at 600 °C is presented by β-calcium polyphosphate β-Са(PO3)2, while β-calcium polyphosphate β-Ca(PO3)2 and tromelite Ca4P6О19 are observed after the thermal treatment at 700 °C. The calcium phosphate powder colored due to presence of amorphous carbon can be used as a photocured suspension component that increases the resolution in stereolithographic printing of pre-ceramic semifinished products with a specified geometry of the pore space of calcium phosphate ceramic matrices. The synthesized powder of double calcium’ammonium pyrophosphate monohydrate Ca(NH4)2P2O7•H2O can be applied as a precursor of biocompatible phases for the fabrication of calcium phosphate ceramics used in medicine for the treatment of bone tissue defects.

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Authors and Affiliations

  1. Department of Chemistry, M. V. Lomonosov Moscow State University, Building 3, 1 Leninskie Gory, 119991, Moscow, Russian Federation

    T. V. Safronova, A. S. Kiselev, T. B. Shatalova & O. T. Gavlina

  2. Department of Materials Science, M. V. Lomonosov Moscow State University, Building 73, 1 Leninskie Gory, 119991, Moscow, Russian Federation

    T. V. Safronova, T. B. Shatalova & Ya. Yu. Filippov

  3. Institute of Mechanics, M. V. Lomonosov Moscow State University, 1 Michurinskii prosp., 119192, Moscow, Russian Federation

    Ya. Yu. Filippov

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  1. T. V. Safronova
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  2. A. S. Kiselev
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  3. T. B. Shatalova
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  4. Ya. Yu. Filippov
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  5. O. T. Gavlina
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Correspondence to T. V. Safronova.

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Dedicated to Academician of the Russian Academy of Sciences V. V. Lunin on the occasion of his 80th birthday.

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 1, pp. 0319–0147, January, 2020.

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Safronova, T.V., Kiselev, A.S., Shatalova, T.B. et al. Synthesis of double ammonium’calcium pyrophosphate monohydrate Ca(NH4)2P2O7•H2O as the p recursor of biocompatible phases of calcium phosphate ceramics. Russ Chem Bull 69, 139–147 (2020). https://doi.org/10.1007/s11172-020-2735-5

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  • DOI: https://doi.org/10.1007/s11172-020-2735-5

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