Abstract
The kinetics of thermal transformations of the energetic compound 2,4,6-tris(2,2,2- trinitroethylnitramino)-1,3,5-triazine (1) and products of this reaction were studied by differential scanning calorimetry, thermogravimetry, IR spectroscopy, single-crystal X-ray diffraction, and powder X-ray diffraction. The kinetic and activation parameters of the decomposition of compound 1 were determined. The polymorphic phase transformation α-1 → β-1 was observed at 105 °C. The kinetics of the solid-state thermal decomposition of compound β-1 was found to be described by the same Arrhenius equation as the decomposition kinetics of 1 in the melt, i.e., the inhibitory effect of the crystal lattice is absent. The factors responsible for this anomaly are discussed.
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Dedicated to Academician of the Russian Academy of Sciences V. V. Lunin on the occasion of his 80th birthday.
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 1, pp. 0118–0124, January, 2020.
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Zakharov, V.V., Chukanov, N.V., Larikova, T.S. et al. Effect of polymorphic phase transitions on stability of energetic compounds. Thermal transformations of 2,4,6-tris(2,2,2-trinitroethylnitramino)-1,3,5-triazine. Russ Chem Bull 69, 118–124 (2020). https://doi.org/10.1007/s11172-020-2732-8
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DOI: https://doi.org/10.1007/s11172-020-2732-8