Abstract
The product of addition of O, O-dialkyldithiophosphoric acid to enamine reacted with the third reaction component of electrophilic nature, for instance, acetyl chloride, α-bromo ether, or sulfenyl bromide. The reaction involving sulfenyl bromide gave the product of reduction of the C—Hal bond of iminium salt and bis(dialkoxythiophosphorylthio) disulfide. This experimentally confirmed the occurrence of the reaction between 2-halo-substituted ald- or ketimines with thio acids via enamine intermediates.
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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 1, pp. 0110–0113, January, 2020.
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Gazizov, M.B., Khairullin, R.A., Kirillina, Y.S. et al. Three component reactions of enamines, O,O-dialkyldithiophosphoric acids, and electrophiles. Russ Chem Bull 69, 110–113 (2020). https://doi.org/10.1007/s11172-020-2730-x
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DOI: https://doi.org/10.1007/s11172-020-2730-x