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Complexes of palladium(II) with N-heterocyclic carbenes from adamantylimidazole as precatalysts for thiophene and imidazole arylation

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Abstract

Complexes of palladium(II) with N-heterocyclic carbenes of the PEPPSI-type were synthesized by the reaction of PdCl2 with 1-adamantyl-3-(R-methyl)-1H-imidazolium salts. These complexes were used as productive precatalysts for substituted thiophene and imidazole arylation by C—H-activation.

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Author information

Authors and Affiliations

  1. Institute of Technical Chemistry, Perm Federal Scientific Center, Ural Branch of the Russian Academy of Sciences, 3 ul. Akad. Koroleva, 614013, Perm, Russian Federation

    M. S. Denisov, A. A. Gorbunov & V. A. Glushkov

  2. Perm State National Research University, 5 ul. Bukireva, 614990, Perm, Russian Federation

    M. V. Dmitriev & V. A. Glushkov

Authors
  1. M. S. Denisov
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  2. M. V. Dmitriev
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  3. A. A. Gorbunov
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  4. V. A. Glushkov
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Corresponding author

Correspondence to M. S. Denisov.

Additional information

Based on the materials of the V International Scientific Conference “Advances in Synthesis and Complexing” (April 22–26, 2019, Moscow, Russia).

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 11, pp. 2039–2047, November, 2019.

The work was financially supported by the Russian Foundation for Basic Research (Project No. 17-03-00456-a).

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Denisov, M.S., Dmitriev, M.V., Gorbunov, A.A. et al. Complexes of palladium(II) with N-heterocyclic carbenes from adamantylimidazole as precatalysts for thiophene and imidazole arylation. Russ Chem Bull 68, 2039–2047 (2019). https://doi.org/10.1007/s11172-019-2664-3

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  • DOI: https://doi.org/10.1007/s11172-019-2664-3

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