Abstract
Adsorption of nitrogen, argon, and methane in a polymer adsorbent MN-200 was studied in the pressure range of 0.1–40 MPa at temperatures of 303, 323, 343, and 363 K. The excess adsorption isotherms were measured, the adsorption volumes were determined, the adsorption isotherms of total content and the characteristic adsorption energies were calculated. Isosteric, integral, and average heats of adsorption were determined.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
V. A. Davankov, M. P. Tsyurupa, Pure Appl. Chem., 1989, 61, 1881.
A. A. Pribylov, S. M. Kalashnikov, V. V. Serpinskii, Bull. Acad. Sci. USSR, Div. Chem. Sci., 1990, 39, 1105.
V. V. Sychev, A. A. Vasserman, V. A. Zagoruchenko, A. D. Kozlov, G. A. Spiridonov, V. A. Tsymarnyy, Termodinamicheskie svoystva metana [Thermodynamic Properties of Methane], Izd-vo standartov, Moscow, 1979, 348 pp. (in Russian).
V. V. Sychev, A. A. Vasserman, A. D. Kozlov, G. A. Spiridonov, V. A. Tsymarnyy, Termodinamicheskie svoystva azota [Thermodynamic Properties of Nitrogen], Izd-vo standartov, Moscow, 1977, 352 pp. (in Russian).
V. A. Rabinovich, A. A. Vasserman, V. I. Nedostup, L. S. Veksler, Termodinamicheskie svoystva neona, argona, kriptona i ksenona [Thermodynamic Properties of Neon, Argon, Krypton, and Xenon], Izd-vo standartov, Moscow, 1976, 636 pp. (in Russian).
A. A. Pribylov, O. G. Larionov, L. G. Shehovtsova, I. A. Kalinnikova, L. D. Belyakova, Russ. Chem. Bull., 2009, 58, 722.
T. S. Yakubov, L. G. Shehovtsova, A. A. Pribylov, Russ. Chem. Bull., 1995, 44, 2277.
V. A. Bakaev, Dokl. AN SSSR, 1966, 167, 369 [Dokl. Acad. Sci. USSR (Engl. Transl.), 1966].
A. A. Lopatkin, Teoreticheskie osnovy fizicheskoy adsorbtsii [Theoretical Foundations of Physical Adsorption], Izd-vo MGU, Moscow, 1983, 344 pp. (in Russian).
V. A. Bakaev, Dr. Sci. Thesis (Phys.-Math.), M. V. Lomonosov Moscow State University, Department of Chemistry, Moscow, 1989, 304 pp. (in Russian).
A. A. Pribylov, K. O. Murdmaa, Russ. Chem. Bull., 2017, 66, 849.
M. M. Dubinin, Adsorbtsiya i poristost’ [Adsorption and Porosity], Izd-vo VAKhZ, Moscow, 1972, 127 pp. (in Russian).
A. A. Pribylov, I. A. Kalinnikova, K. O. Murdmaa, Russ. Chem. Bull., 2016, 65, 972.
A. A. Pribylov, K. O. Murdmaa, O. V. Solovtsova, M. K. Knyazeva, Russ. Chem. Bull., 2018, 67, 1807.
J. O. Herschfelder, Ch. F. Curtiss, R. B. Bird, Molecular Theory of Gases and Liquids, University of Wisconsin, John Wiley and Sons, Inc., New York; Chapman and Hall, London, 1954.
Author information
Authors and Affiliations
Corresponding author
Additional information
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 11, pp. 2002–2008, November, 2019.
This work was financially supported by the Federal Target Program “Research and Development in Priority Growth Directions of the Russian Science and Technology Complex for 2014–2020” (topic “Development and Research of a Low-temperature Adsorption System for Accumulating Natural Gas with Increased Fire and Explosion Safety and Energy Efficiency”, agreement No. 14.607.21.0079).
Rights and permissions
About this article
Cite this article
Pribylov, A.A., Murdmaa, K.O. Adsorption of gases on a polymer adsorbent MN-200 in the region of supercritical temperatures and pressures. Russ Chem Bull 68, 2002–2008 (2019). https://doi.org/10.1007/s11172-019-2659-0
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11172-019-2659-0