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Experimental determination of the standard enthalpy of formation of 4H,8H-bis(furazano)[3,4-b:3′,4′-e]pyrazine and evaluation of its performance as a dispersant of solid fuels

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Abstract

The energy of combustion ΔH°c of 4H,8H-bis(furazano)[3,4-b:3′,4′-e]pyrazine (BFP) was measured by calorimetry in the oxygen atmosphere and the standard enthalpy of formation ΔH°f was calculated. The real ΔH°f value was found to be 33 kJ mol−1 higher than reported before. The obtained results were used for correction of the evaluated efficiency of using BFP as a solid fuel dispersant for rocket ramjet engines, which showed high BFP performance.

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Authors and Affiliations

  1. Institute of Problems of Chemical Physics, Russian Academy of Sciences, 1 prosp. Akad. Semenova, 142432, Chernogolovka, Moscow Region, Russian Federation

    D. B. Lempert, A. I. Kazakov, A. V. Nabatova & L. S. Yanovskii

  2. N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991, Moscow, Russian Federation

    A. B. Sheremetev & A. G. Gladyshkin

  3. Department of Chemistry, M. V. Lomonosov Moscow State University, Build. 3, 1 Leninskie Gory, 119991, Moscow, Russian Federation

    L. S. Yanovskii

Authors
  1. D. B. Lempert
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  2. A. I. Kazakov
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  3. A. B. Sheremetev
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  4. A. G. Gladyshkin
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  5. A. V. Nabatova
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  6. L. S. Yanovskii
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Correspondence to D. B. Lempert.

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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 10, pp. 1856–1859, October, 2019.

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Lempert, D.B., Kazakov, A.I., Sheremetev, A.B. et al. Experimental determination of the standard enthalpy of formation of 4H,8H-bis(furazano)[3,4-b:3′,4′-e]pyrazine and evaluation of its performance as a dispersant of solid fuels. Russ Chem Bull 68, 1856–1859 (2019). https://doi.org/10.1007/s11172-019-2635-8

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  • DOI: https://doi.org/10.1007/s11172-019-2635-8

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