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New 2-(2-pyridyl)-substituted benzothiazoles with polyethylene glycol substituents

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Abstract

An approach for the synthesis of new organic ligands combining in their structure pyridine, benzothiazole, and polyethylene glycol fragments was developed, proceeding from 6-hydroxy-2-(pyridin-2-yl)benzothiazole and mono- or ditosyl-substituted polyethylene glycols. The ligand 2-(2-{[2-(pyridin-2-yl)benzothiazol-6-yl]oxy}ethoxy)ethanol (L) in the reaction with Cu(ClO4)2•6 H2O and CuCl2•2 H2O formed coordination compounds of the composition L2Cu(ClO4)2•7 H2O and LCuCl2•0.5 H2O, respectively.

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Authors and Affiliations

  1. Department of Chemistry, Lomonosov Moscow State University, Build. 3, 1 Leninskie Gory, 119991, Moscow, Russian Federation

    E. S. Barskaya, V. V. Shorokhov, A. V. Rzheutsky, A. D. Khudyakov, I. V. Yudin, V. A. Tafeenko, N. V. Zyk & E. K. Beloglazkina

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  1. E. S. Barskaya
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  2. V. V. Shorokhov
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  3. A. V. Rzheutsky
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  4. A. D. Khudyakov
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  5. I. V. Yudin
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  6. V. A. Tafeenko
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  7. N. V. Zyk
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  8. E. K. Beloglazkina
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Correspondence to E. K. Beloglazkina.

Additional information

Based on the materials of the V All-Russian Organic Chemistry Conference (ROCC-V) (September 10–14, 2018, Vladikavkaz, Russia).

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Barskaya, E.S., Shorokhov, V.V., Rzheutsky, A.V. et al. New 2-(2-pyridyl)-substituted benzothiazoles with polyethylene glycol substituents. Russ Chem Bull 68, 638–643 (2019). https://doi.org/10.1007/s11172-019-2468-5

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  • DOI: https://doi.org/10.1007/s11172-019-2468-5

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