Skip to main content
SpringerLink
Log in

New copolymers of perfluoro-2-ethyl-2-methyl-1,3-dioxole and perfluorovinyl ether with low non-monotonic refractive index

  • Full Article
  • Published:
Russian Chemical Bulletin Aims and scope

Abstract

Copolymers of perfluoro-2-ethyl-2-methyl-1,3-dioxole and perfluoro-5-methyl-3,6-dioxanon-1-ene were synthesized using high-pressure technique without initiators. Copolymers have molecular weight of (1.2–4) • 104 and possess high optical transparency in the telecommunication C-band region of 1530–1565 nm. Refractive index n of copolymers as a function of ether mol.% in the macromolecule x was investigated. It is established that the curve n(x) is non-monotonic, the difference of refractive indices of copolymers with various x differs by Δn = 0.015. The synthesized materials are amorphous, capable of film formation, and can be used for the fabrication of optical fibers and integrated optical waveguides with numerical aperture NA from 0.13 to 0.2, with waveguiding core and cladding made of perfluorinated materials.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. W. Groh, Makromol. Chem., 1988, 189, 2861.

    Article  CAS  Google Scholar 

  2. N. Tanio, Y. Koike, Polymer J., 2000, 32, 43.

    Article  CAS  Google Scholar 

  3. W. Groh, A. Zimmermann, Macromolecules, 1991, 24, 6660.

    Article  CAS  Google Scholar 

  4. M. Zhou, Opt. Eng., 2002, 41, 1631.

    Article  CAS  Google Scholar 

  5. V. N. Serova, Opticheskie i drugie materiali na osnove prozrachnikh polimerov [Optical and Other Materials Based on Transparent Polymers], KSTU, Kazan, 2010, 540 pp. (in Russian).

    Google Scholar 

  6. A. Vitale, R. Bongiovanni, B. Ameduri, Chem. Rev., 2015, 115, 8835.

    Article  CAS  PubMed  Google Scholar 

  7. M. C. J. Lagre, L. Poladian, G. W. Barton, M. A. van Eijkelenborg, Microstructured Polymer Optical Fibers, Springer Science, 2008, 260 pp.

    Google Scholar 

  8. L. Eldada, L.W. Shacklette, IEEE J. Selected Topics in Quantum Electronics, 2000, 6, 54.

    Article  CAS  Google Scholar 

  9. V. I. Sokolov, A. S. Akhmanov, S. M. Igumnov, S. I. Molchanova, A. G. Savelev, A. A. Tyutyunov, E. V. Khaydukov, K. V. Khaydukov, V. Ya. Panchenko, Bull. RFBR, 2014, 83, 78 (in Russian).

    Google Scholar 

  10. M. K. Yang, R. H. French, E. W. Tokarsky, J. Micro/Nanolith. MEMS MOEMS, 2008, 7, 033010–1.

    Article  CAS  Google Scholar 

  11. A. Lacraz, M. Polis, A. Theodosiou, C. Koutsides, K. Kalli, Proc. of SPIE, 2015, 9507, 95070K–1.

    Article  Google Scholar 

  12. C. Mattevi, F. Colléaux, H. Kim, Y.H. Lin, K.T. Park, M. Chhowalla, Nanotechnology, 2012, 23, 344017.

    Article  CAS  PubMed  Google Scholar 

  13. A. A. Zharov, I. A. Guzyaeva, Russ. Chem. Bull., 2010, 59, 1225.

    Article  CAS  Google Scholar 

  14. V. I. Sokolov, V. E. Boyko, I. O. Goriachuk, S. M. Igumnov, S. I. Molchanova, Yu. E. Pogodina, E. V. Polunin, Russ. Chem. Bull., 2017, 66, 1284.

    Article  CAS  Google Scholar 

  15. http://www.fluorine1.ru.

  16. V. I. Sokolov, N. V. Marusin, V. Ya. Panchenko, A. G. Savelyev, V. N. Seminogov, E. V. Khaydukov, Quantum Electronics, 2013, 43, 1149.

    Article  CAS  Google Scholar 

  17. E. V. Polunin, S. I. Molchanova, Yu. E. Pogodina, V. I. Sokolov, I. V. Zavarzin, Fluorine Notes, 2017, 114, 5.

    Google Scholar 

  18. J. Brand, G. Eglinton, Applications of Spectroscopy to Organic Chemistry, 1967, 280 pp.

    Google Scholar 

  19. P. Resnik, 5th Int. Symposia for Fluorine Chem., Moscow, 1969, p. 6.

    Google Scholar 

  20. A. A. Glazkov, Ph. D. Thesis (chem), N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, 1984, 141 pp. (in Russian).

Download references

Author information

Authors and Affiliations

  1. Federal Scientific Research Centre “Crystallography and Photonics”, Russian Academy of Sciences, 17A ul. Butlerova, 117342, Moscow, Russian Federation

    V. I. Sokolov, I. O. Goriachuk & S. I. Molchanova

  2. N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991, Moscow, Russian Federation

    I. V. Zavarzin, Yu. E. Pogodina, E. V. Polunin & A. A. Yarosch

Authors
  1. V. I. Sokolov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. I. O. Goriachuk
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. I. V. Zavarzin
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. S. I. Molchanova
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Yu. E. Pogodina
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. E. V. Polunin
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. A. A. Yarosch
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to V. I. Sokolov.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Sokolov, V.I., Goriachuk, I.O., Zavarzin, I.V. et al. New copolymers of perfluoro-2-ethyl-2-methyl-1,3-dioxole and perfluorovinyl ether with low non-monotonic refractive index. Russ Chem Bull 68, 559–564 (2019). https://doi.org/10.1007/s11172-019-2454-y

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11172-019-2454-y

Key words

Search

Navigation