Skip to main content
SpringerLink
Log in

Equilibrium, kinetic, and thermodynamic studies on the sorption of some heavy metal ions by the phosphorus-containing polymer sorbent

  • Full Article
  • Published:
Russian Chemical Bulletin Aims and scope

Abstract

The sorption of Cu+2, Ni+2, Co+2, and Zn+2 ions onto the phosphorus-containing sorbent were studied as a function of the contact time, temperature, and concentration of the initial metal ions. The equilibrium studies are presented by the Langmuir, Freundlich, and Temkin isotherm models. The sorption data are well described by the Langmuir isotherm model, and they also can be simulated by the Freundlich isotherm model. The pseudo-first-order, pseudo-second-order, and intraparticle diffusion models were applied to test the experimental data of the kinetic studies. The pseudo-second-order kinetic model provided the best correlation of the experimental data compared to the other kinetic models. The sorption capacity of the metal ions increased with temperature increasing. The positive value of enthalpy (ΔH°) and the negative value of Gibbs free energy (ΔG°) indicated that the sorption process was endothermic and spontaneous.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. J. K. Dunnick, B. A. Fowler, in Toxicity of Inorganic Compounds, Eds H. G. Seller, H. Sigel, A. Sigel, Marcel Dekker, New York, 1988.

  2. S. Ciurli, S. Mangani, in Handbook of Metalloproteins, Eds I. Bertini, A. Sigel, H. Sigel, Marcel Dekker, New York, 2001.

  3. Pollutants in Urban Waste Water and Sewage Sludge. Final Report Prepared by ICON, IC Consultants Ltd, London United Kingdom, 2001; http://ec.europa.eu/environment/archives/waste/sludge/pdf/sludge_pollutants.pdf.

  4. M. Yavuz, F. Gode, S. Osmert, Y. Sharma, Chem. Eng. J., 2008, 137, 453.

    Article  CAS  Google Scholar 

  5. M. Mulder, Basic Principles of Membrane Technology, Kluwer Academic Publisher, Holland, 1996.

    Book  Google Scholar 

  6. M. C. Basso, E. G. Cerrella, A. L. Cukierman, Ind. Eng. Chem. Res., 2002, 41, 180.

    Article  CAS  Google Scholar 

  7. S. Gomez-Salazar, J. S. Lee, J. C. Heydweiller, L. S. Tavlarides, Ind. Eng. Chem. Res., 2003, 42, 3403.

    Article  CAS  Google Scholar 

  8. C. P. Huang, Y. C. Chung, M. R. Liou, J. Hazard. Mater., 1996, 45, 265.

    Article  CAS  Google Scholar 

  9. J. R. Evans, W. G. Davids, J. D. MacRae, A. Amirbahman, Water Res., 2002, 36, 3219.

    Article  CAS  PubMed  Google Scholar 

  10. M. V. Dinu, E. S. Dragan, A. W. Trochimczuk, Desalination, 2009, 249, 374.

    Article  CAS  Google Scholar 

  11. M. Karnib, A. Kabbani, H. Holail, Z. Olama, Energy Procedia, 2014, 50, 113.

    Article  CAS  Google Scholar 

  12. B. Samiey, C. Cheng, J. Wu, Materials, 2014, 7, 673.

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  13. M. Soylak, L. Elci, M. Dogan, Anal. Lett., 2000, 33, 513.

    Article  CAS  Google Scholar 

  14. F. Wang, L. Wang, J. Li, X. Sun, W. Han, Trans. Nonferrous. Met. Soc. China, 2009, 19, 740.

    Article  CAS  Google Scholar 

  15. G. Ahmetli, E. J. Tarlan, Appl. Polym. Sci., 2007, 104, 2696.

    Article  CAS  Google Scholar 

  16. A. Dyer, in Encyclopedia of Separation Science, Ed. I. D. Wilson, Academic Press, New York, 2000.

  17. H. Deveci, G. Ahmetli, M. Ersoz, R. Kurbanli, Appl. Polym. Sci., 2009, 112, 1192.

    Article  CAS  Google Scholar 

  18. F. Kanwal, M. Imran, L. Mitu, Z. Rashid, H. Razza, E-J. Chem., 2012, 9, 621.

    Article  CAS  Google Scholar 

  19. A. W. Trochimczuk, S. Czerwinska, React. Funct. Polym., 2005, 63, 215.

    Article  CAS  Google Scholar 

  20. A. W. Trochimczuk, React. Funct. Polym., 2000, 44, 9.

    Article  CAS  Google Scholar 

  21. A. W. Trochimczuk, Separ. Sci. Technol., 2002, 37, 3201.

    Article  CAS  Google Scholar 

  22. A. W. Trochimczuk, Solvent. Extr. Ion. Exc., 2001, 19, 301.

    Article  CAS  Google Scholar 

  23. R. Alosmanov, K. Wolski, G. Matuschek, A. Magerramov, A. Azizov, R. Zimmermann, E. Aliyev, S. Zapotoczny, J. Therm. Anal. Calorim., 2017, 130, 799.

    Article  CAS  Google Scholar 

  24. R. M. Alosmanov, A. A. Azizov, A. M. Magerramov, Russ. J. Gen. Chem., 2011, 81, 1477.

    Article  CAS  Google Scholar 

  25. V. M. Akhmedov, S. Alfadul, A. M. Maharramov, A. A. Azizov, R. M. Alosmanov, I. A. Buniyad-Zadeh, Polish J. Chem. Technol., 2015, 17, № 2, 112.

    Article  CAS  Google Scholar 

  26. A. Dabrowski, Adv. Colloid Inter. Sci., 2001, 93, 135.

    Article  CAS  Google Scholar 

  27. Y. S. Ho, D. A. Wase, C. F. Forster, Water SA, 1996, 22, 219.

    CAS  Google Scholar 

  28. E. I. Unuabonah, B. I. Adebowale, J. Hazar. Mater., 2007, 144, 386.

    Article  CAS  Google Scholar 

  29. Y. S. Ho, C. T. Huang, H. W. Huang, Process Biochem., 2002, 37, 1421.

    Article  CAS  Google Scholar 

  30. Y. Yua, Y. Yi. Zhuang, Z. H. Wang, J. Colloid Inter. Sci., 2001, 242, 288.

    Article  CAS  Google Scholar 

  31. C. H. Giles, D. Smith, A. Huitson, J. Colloid Inter. Sci., 1974, 47, 755.

    Article  CAS  Google Scholar 

  32. I. Langmuir, J. Am. Chem. Soc., 1916, 38, 2221.

    Article  CAS  Google Scholar 

  33. H. M. F. Freundlich, Z. Phys. Chem., 1906, 57, 385.

    CAS  Google Scholar 

  34. M. I. Temkin, V. Pyzhev, Acta. Phys. Chim. USSR, 1940, 12, 327.

    CAS  Google Scholar 

  35. Yu. D. Tret’yakov, L. I. Martynenko, A. N. Grigor’ev, A. Yu. Tsivadze, Neorganicheskaya khimiya [Inorganic Chemistry], Vol. 2, Khimiya, Moscow, 2001, p. 483 (in Russian).

    Google Scholar 

  36. Y. S. Ho, G. McKay, Water Res., 2000, 34, 735.

    Article  CAS  Google Scholar 

  37. M. Yurdakoc, Y. Scki, S. K. Yuedakoc, J. Coll. Inter. Sci., 2005, 286, 440.

    Article  CAS  Google Scholar 

  38. F. C. Wu, R. L. Tseng, R. S. Juang, Chem. Eng. J., 2009, 153, 1.

    Article  CAS  Google Scholar 

  39. R. M. Alosmanov, J. Serb. Chem. Soc., 2016, 81, 907.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. M. Nagiev Institute of Catalysis and Inorganic Chemistry, Azerbaijan National Academy of Sciences, 113 prosp. H. Javid, AZ 1143, Baku, Azerbaijan

    V. M. Akhmedov

  2. Department of Chemistry, Baku State University, 23 ul. Z. Khalilova, AZ 1148, Baku, Azerbaijan

    A. M. Maharramov, A. A. Azizov, R. M. Alosmanov, I. A. Bunyad-Zadeh & S. B. Aliyeva

Authors
  1. V. M. Akhmedov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. A. M. Maharramov
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. A. A. Azizov
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. R. M. Alosmanov
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. I. A. Bunyad-Zadeh
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. S. B. Aliyeva
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to V. M. Akhmedov.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Akhmedov, V.M., Maharramov, A.M., Azizov, A.A. et al. Equilibrium, kinetic, and thermodynamic studies on the sorption of some heavy metal ions by the phosphorus-containing polymer sorbent. Russ Chem Bull 68, 514–520 (2019). https://doi.org/10.1007/s11172-019-2447-x

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11172-019-2447-x

Key words

Search

Navigation