Skip to main content
SpringerLink
Log in

Water gas shift reaction in the presence of palladium complexes with diphenyl-m-sulfophenylphosphine

  • Full Article
  • Published:
Russian Chemical Bulletin Aims and scope

Abstract

A homogeneous catalytic system containing palladium(ii) halides, diphenyl-m-sulfo-phenylphosphine (or palladium halide complexes with diphenyl-m-sulfophenylphosphine) and hydrohalic acid was developed and studied in the liquid-phase water gas shift reaction. The system based on palladium bromide and hydrobromic acid in aqueous acetic acid (20–40 vol.%) showed the highest activity. The dependences of the initial reaction rate on the concentrations of reagents and catalyst components were studied, a mechanism for the process was proposed, and a kinetic model was developed and found to agree well with experimental results.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. I. I. Moiseev, Kinet. Catal., 2001, 42, 1.

    Article  CAS  Google Scholar 

  2. I. Chorkendorff, J. W. Niemantsverdriet, Concepts of Modern Catalysis and Kinetics, WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim, 2007.

    Google Scholar 

  3. E. G. Chepaikin, M. L. Khidekel’, Koord. Khim., 1982, 8, 1011 [Sov. J. Coord. Chem. (Engl. Transl.), 1982, 8, No. 8].

    CAS  Google Scholar 

  4. V. N. Zudin, V. D. Chinakov, V. M. Nekipelov, V. A. Rogov, V. A. Likholobov, Yu. I. Yermakov, J. Mol. Catal., 1989, 52, 27.

    Article  CAS  Google Scholar 

  5. E. G. Chepaikin, A. P. Bezruchenko, E. N. Sal’nikova, F. Joo, Z. Toth, M. T. Beck, M. L. Khidekel’, Bull. Acad. Sci. USSR, Div. Chem. Sci., 1989, 38, 476.

    Article  Google Scholar 

  6. M. A. Fernandez, M. Meza, M. Mediavillam, C. Longo, S. A. Moya, F. Lopez, P. Baricelli, A. J. Pardey, Anales de Quimica (Int. Ed.), 1998, 94, 127.

    CAS  Google Scholar 

  7. S. Luukkanen, P. Homanen, M. Haukka, T. A. Pakkanen, A. Deronzier, S. Chardon-Noblat, D. Zsoldos, R. Ziessel, Appl. Catal., 1999, 185, 157.

    Article  CAS  Google Scholar 

  8. S. Werner, N. Szesni, R. W. Fischer, M. Haumann, P. Wasserscheid, Phys. Chem. Chem. Phys, 2009, 11, 10817.

    Article  CAS  PubMed  Google Scholar 

  9. S. Werner, N. Szesni, A. Bitterman, M. J. Schneider, P. Harter, M. Haumann, P. Wasserscheid, Appl. Catal., A: General, 2010, 377, 70.

    Article  CAS  Google Scholar 

  10. A. J. Pardey, C. Longo, Coord. Chem. Rev., 2010, 254, 254.

    Article  CAS  Google Scholar 

  11. Y. Zhang, C. Zuo, C. Li, X. Li, S. Zhang, Green Chem., 2016, 18, 4704.

    Article  CAS  Google Scholar 

  12. E. G. Chepaikin, A. P. Bezruchenko, M. L. Khidekel’, Bull. Acad. Sci. USSR, Div. Chem. Sci., 1980, 29, 2666.

    Google Scholar 

  13. S. Ahrland, J. Chatt, N. R. Davis, A. A. Williams, J. Chem. Soc., 1958, 276.

  14. T. A. Stephenson, S. M. Morehouse, A. R. Powell, J. P. Heffer, G. Wilkinson, J. Chem. Soc., 1965, 3632.

  15. E. G. Chepaikin, A. P. Bezruchenko, Yu. G. Noskov, Proc. Int. Conf. “Mechanisms of Catalytic Reactions”(St. Petersburg, October22–25, 2012), St. Petersburg, 2012, p. 137 (in Russian).

  16. V. B. Kogan, V. M. Fridman, V. V. Kafarov (Ed. V. V. Kafarov), Spravochnikpo rastvorimosti [Solibility Handbook], Izd. Akad. Nauk SSSR, Moscow—Leningrad, 1962, Vol. I, Book 2, p. 1053, Table No. 4187 (in Russian).

    Google Scholar 

  17. D. V. Sokol’skii, Ya. A. Dorfman, Kataliz ligandami v vodnykh rastvorakh [Ligand Catalysis in Aqueous Solutions], Nauka, Alma-Ata, 1972, p. 336 (in Russian).

    Google Scholar 

  18. T. Inatomi, Y. Koga, K. Matsubara, Molecules, 2018, 23, 140.

    Article  CAS  PubMed Central  Google Scholar 

  19. L. G. Brook, O. N. Temkin, Z. V. Goncharova, I. S. Ustenko, V. R. Flid, React. Kinet. Catal. Lett., 1978, 9, 303.

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. A. G. Merzhanov Institute of Structural Macrokinetics and Materials Science, Russian Academy of Sciences, 8 ul. Akad. Osipyana, 142432, Chernogolovka, Moscow Region, Russian Federation

    E. G. Chepaikin, A. P. Bezruchenko & G. N. Menchikova

  2. LLC United Research and Development Centre, Build. 2, 55/1 Leninsky prosp., 119333, Moscow, Russian Federation

    Yu. G. Noskov

Authors
  1. E. G. Chepaikin
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. A. P. Bezruchenko
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. G. N. Menchikova
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Yu. G. Noskov
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to E. G. Chepaikin.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Chepaikin, E.G., Bezruchenko, A.P., Menchikova, G.N. et al. Water gas shift reaction in the presence of palladium complexes with diphenyl-m-sulfophenylphosphine. Russ Chem Bull 68, 493–499 (2019). https://doi.org/10.1007/s11172-019-2444-0

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11172-019-2444-0

Key words

Search

Navigation