A synthetic procedure was designed to prepare formulations from Ftorsam-39 monomer (perfluoro-2,5-dimethyl-3,6-dioxanonoic acid triethoxysilylpropylamide) with SKF-26(ONM) fluorine rubber (poly(vinylidene fluoride-co-hexafluoropropylene)) in a presence of AGM-9 (γ-aminopropyltriethoxysilane) as a catalyst and co-reagent. The content of fluorine rubber in the compositions was varied from 10 to 54 wt.%. Thermal properties of the formulations obtained with the ratio Ftorsam-39: SKF-26(ONM): AGM-9 = 40: 54: 6 (wt.%) were assessed using thermomechanical and thermogravimetric analysis and differential scanning calorimetry.
This is a preview of subscription content, log in to check access.
Buy single article
Instant access to the full article PDF.
Price includes VAT for USA
Subscribe to journal
Immediate online access to all issues from 2019. Subscription will auto renew annually.
This is the net price. Taxes to be calculated in checkout.
Z. N. Nudelman, Ftorkauchuki: osnovy, pererabotka, primenenie [Fluorine Rubber: Basics, Processing, Application], Reklamamaster, 2006, p. 185 (in Russian).
S. P. Krukovsky, A. A. Yarosh, A. A. Glazkov, D. V. Batizat, T. N. Redina, J. Fluorine Chem., 1999, 96, 31.
A. A. Yarosh, S.P. Krukovsky, T. A. Pryakhina., V. M. Kotov, B. G. Zavin, A. M. Sakharov, Mendeleev Commun., 2006, 190.
S. P. Krukovsky, A. A. Yarosh, D. V. Batizat, A. A. Glazkov, M. Yu. Popovich, O. U. Smirnova, A. M. Sakharov, in Sbornik nauchnikh trudov FGUP Rossiskiy nauchniy zentr Prikladnaya khimiya [Collection of Scientific Works of FSUE Russian Scientific Center Applied Chemistry], Anniversary Edition, St. Petersburg, 2009, p. 191 (in Russian).
S. M. Gaidar, A. A. Yarosh, S. P. Krukovsky, M. M. Gurkov, V. A. Khudorozhkova, Pat. RF, No. 2425175, 27.07.2011, CA 2011, 115, 247624.
A.M. Sakharov, M. Yu. Popovich, S. P. Krukovsky, Fluorine Notes (Engl. Transl.), 2017, 5, 114.
Z. N. Nudelman, S. P. Krukovsky, L. N. Lavrova, Yu. L. Morozov, A. A. Yarosh, E. E. Sheveleva, Pat. RF No. 2203886, 10.05.2003, CA 2003, 140, 254847.
K. Pasiorik, Strukturirovanie kauchukov [Rubber Structuring], Mir, 1975, p. 244 (in Russian).
Yu. A. Panshin, S. G. Malkevich, C. S. Dunaevskaya, Ftoroplasty [Fluoroplasts], Khimiya, Leningrad, 1978, p. 172 (in Russian).
Dedicated to Corresponding Member of the Russian Academy of Sciences G. I. Nikishin in occasion of his 90th anniversary.
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 2, pp. 0449–0452, February, 2019.
About this article
Cite this article
Sakharov, A.M., Popovich, M.Y. & Krukovsky, S.P. Preparation and thermal behavior of the formulation of Ftorsam-39 with SKF-26(ONM) fluorine rubber. Russ Chem Bull 68, 449–452 (2019). https://doi.org/10.1007/s11172-019-2407-5
- Ftorsam-39 monomer
- Ftorsam-39 polymer
- SKF-26(ONM) fluorine rubber
- thermomechanical analysis
- thermogravimetric analysis