Preparation and thermal behavior of the formulation of Ftorsam-39 with SKF-26(ONM) fluorine rubber

Abstract

A synthetic procedure was designed to prepare formulations from Ftorsam-39 monomer (perfluoro-2,5-dimethyl-3,6-dioxanonoic acid triethoxysilylpropylamide) with SKF-26(ONM) fluorine rubber (poly(vinylidene fluoride-co-hexafluoropropylene)) in a presence of AGM-9 (γ-aminopropyltriethoxysilane) as a catalyst and co-reagent. The content of fluorine rubber in the compositions was varied from 10 to 54 wt.%. Thermal properties of the formulations obtained with the ratio Ftorsam-39: SKF-26(ONM): AGM-9 = 40: 54: 6 (wt.%) were assessed using thermomechanical and thermogravimetric analysis and differential scanning calorimetry.

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Correspondence to S. P. Krukovsky.

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Dedicated to Corresponding Member of the Russian Academy of Sciences G. I. Nikishin in occasion of his 90th anniversary.

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 2, pp. 0449–0452, February, 2019.

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Sakharov, A.M., Popovich, M.Y. & Krukovsky, S.P. Preparation and thermal behavior of the formulation of Ftorsam-39 with SKF-26(ONM) fluorine rubber. Russ Chem Bull 68, 449–452 (2019). https://doi.org/10.1007/s11172-019-2407-5

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Key words

  • Ftorsam-39 monomer
  • Ftorsam-39 polymer
  • SKF-26(ONM) fluorine rubber
  • AGM-9
  • thermomechanical analysis
  • thermogravimetric analysis