Substrate-induced luminescence response of terbium-containing polymeric vesicles doped with the tetra- and bis-1,3-diketone derivatives of calix[4]arenes bearing nonyl substituents at the lower rims


Polymeric aggregates (~100 nm) based on polydiacetylenic acid doped with the luminescent TbIII complexes with the tetra- and bis-1,3-diketonate derivatives of calix[4]arenes with nonyl substituents at the lower rims are considered as potential nanosensors. The obtained colloidally stable mixed aggregates can generate a substrate-induced luminescent response in aqueous solutions of 2,2´,6´,2´´-terpyridine in the micromolar concentration range due to the coordination of the latter by TbIII ions on the aggregate surface.

This is a preview of subscription content, log in to check access.


  1. 1.

    J. Elistratova, B. Akhmadeev, R. Zairov, A. Dovzhenko, S. Podyachev, S. Sudakova, V. Syakaev, R. Jelinek, S. Kolusheva, A. Mustafina, J. Mol. Liq., 2018, 268, 463.

    CAS  Article  Google Scholar 

  2. 2.

    J. Elistratova, B. Akhmadeev, A. Gubaidullin, M. A. Shestopalov, A. Solovieva, K. Brylev, K. Kholin, I. Nizameev, I. Ismaev, M. Kadirov, A. Mustafina, Mater. Des., 2018, 146, 49.

    CAS  Article  Google Scholar 

  3. 3.

    J. Elistratova, B. Akhmadeev, V. Korenev, M. Sokolov, I. Nizameev, A. Gubaidullin, A. Voloshina, A. Mustafina, Soft Matter, 2018, 14, 7916.

    CAS  Article  Google Scholar 

  4. 4.

    J. Elistratova, B. Akhmadeev, A. Gubaidullin, V. Korenev, M. Sokolov, I. Nizameev, A. Stepanov, I. Ismaev, M. Kadirov, A. Voloshina, A. Mustafina, New J. Chem., 2017, 41, 5271.

    CAS  Article  Google Scholar 

  5. 5.

    J. S. Casas, M. S. Garcia-Tasende, A. Sanchez, J. Sordo, A. Touceda, Coord. Chem. Rev., 2007, 251, 1561.

    CAS  Article  Google Scholar 

  6. 6.

    C. Guanci, R. Pinalli, S. Aime, E. Gianolio, L. Lattuada, G. B. Giovenzana, Tetrahedron Lett., 2015, 56, 1994.

    CAS  Article  Google Scholar 

  7. 7.

    J. Kido, Y. Okamoto, Chem. Rev., 2002, 102, 2357.

    CAS  Article  Google Scholar 

  8. 8.

    P. Caravan, J. J. Ellison, T. J. McMurry, R. B. Lauffer, Chem. Rev., 1999, 99, 2293.

    CAS  Article  Google Scholar 

  9. 9.

    A. L. Gassner, C. Duhot, J. C. Bunzli, A. S. Chauvin, Inorg. Chem., 2008, 47, 7802.

    CAS  Article  Google Scholar 

  10. 10.

    S. Cotton, Lanthanide and Actinide Chemistry, John Wiley&Sons, West Sussex, England, 2006.

    Google Scholar 

  11. 11.

    J. R. Lakowicz, Principles of Fluorescence Spectroscopy, Springer Science Business Media, Singapore, 2006.

    Google Scholar 

  12. 12.

    J. C. Bunzli, S. Comby, A. S. Chauvin, C. D. Vandevyve, J. Rare Earths, 2007, 25, 257.

    Article  Google Scholar 

  13. 13.

    J.-C. G. Bünzli, J. Lumin., 2016, 170, 866.

    Article  Google Scholar 

  14. 14.

    S. N. Podyachev, G. Sh. Gimazetdinova, S. N. Sudakova, D. V. Lapaev, V. V. Syakaev, R. N. Nagimov, Zh. Org. Khim., 2017, 87, 1476–1486 [Russ. J. Org. Chem. (Engl. Transl.), 2017, 87].

    Google Scholar 

  15. 15.

    K. Binnemans, K. A. Gschneidner, J.-C. G. Bünzli, V. K. Pecharsky, Handbook on the Physics and Chemistry of Rare Earths, Elsevier Science, North Holland, 2005, 35, 107.

    Article  Google Scholar 

  16. 16.

    Zh. Wei, K. Ujiiye-Ishii, A. Masuhara, H. Kasai, Sh. Okada, H. Matsune, T. Asahi, H. Masuhara, H. Nakanishi, J. Nanosci. Nanotechnol., 2005, 5, 937.

    CAS  Article  Google Scholar 

  17. 17.

    R. Jelinek, S. Kolusheva, Biotechnol. Adv., 2001, 19, 109.

    CAS  Article  Google Scholar 

  18. 18.

    J. P. Yapor, A. Alharby, C. Gentry-Weeks, M. M. Reynolds, A. K. M. Mashud Alam, Y. V. Li, ACS Omega, 2017, 2, 7334.

    CAS  Article  Google Scholar 

  19. 19.

    E. N. Shamsutdinova, R. Zairov, A. Mustafina, S. Podyachev, S. Sudakova, I. Nizameev, M. Kadirov, R. Amirov, Colloids Surf. A, 2015, 482, 231.

    CAS  Article  Google Scholar 

  20. 20.

    R. Zairov, A. Mustafina, N. Shamsutdinova, I. Nizameev, B. Moreira, S. Sudakova, S. Podyachev, A. Fattakhova, G. Safina, I. Lundstrom, A. Gubaidullin, A. Vomiero, Scientific Reports, 2017, 7.

    Google Scholar 

  21. 21.

    L. G. Koreneva, A. V. Viktorov, L. I. Barsukov, V. F. Zolin, L. D. Bergelson, Biophys. J., 1978, 23, 634.

    Google Scholar 

  22. 22.

    S. S. Asha, A. N. Ananth, G. V. Kumari, B. Prakash, S. P. Jose, M. A. J. Rajan, Adv. Nat. Sci.: Nanosci. Nanotechnol., 2017, 8.

    Google Scholar 

  23. 23.

    S. Kolusheva, R. Zadmard, T. Schrader, R. Jelinek, J. Am. Chem. Soc., 2006, 128, 13592.

    CAS  Article  Google Scholar 

  24. 24.

    A. C. S. Pires, N. F. F. Soares, L. H. M. Silva, M. C. H. Silva, A. B. Mageste, R. F. Soares, A. V. N. C. Teixeira, N. J. Andrade, J. Phys. Chem. B, 2010, 114, 13365.

    CAS  Article  Google Scholar 

  25. 25.

    A. Potisatityuenyong, G. Tumcharern, S. T. Dubas, M. Sukwattanasinitt, J. Colloid Interface Sci., 2006, 304, 45.

    CAS  Article  Google Scholar 

  26. 26.

    M. L. Gou, G. Guo, J. Zhang, K. Men, J. Song, F. Luo, X. Zhao, Z. Y. Qian, Y. Q. Wei, Sens. Actuator B-Chem., 2010, 150, 406.

    CAS  Article  Google Scholar 

  27. 27.

    T. Pattanatornchai, N. Charoenthai, R. Traiphol, J. Colloid Interface Sci., 2014, 432, 176.

    CAS  Article  Google Scholar 

  28. 28.

    A. Potisatityuenyong, R. Rojanathanes, G. Tumcharern, M. Sukwattanasinitt, Langmuir, 2008, 24, 4461.

    CAS  Article  Google Scholar 

  29. 29.

    S. Kolusheva, E. Wachtel, R. Jelinek, J. Lipid Res., 2003, 44, 65.

    CAS  Article  Google Scholar 

  30. 30.

    N. Charoenthai, T. Pattanatornchai, S. Wacharasindhu, M. Sukwattanasinitt, R. Traiphol, J. Colloid Interface Sci., 2011, 360, 565.

    CAS  Article  Google Scholar 

  31. 31.

    S. Okado, S. Peng, W. Spevak, D. Charych, Acc. Chem. Res., 1998, 31, 229.

    Article  Google Scholar 

  32. 32.

    S. Kolusheva, T. Shahal, R. Jelinek, J. Am. Chem. Soc., 2000, 122, 776.

    CAS  Article  Google Scholar 

  33. 33.

    A. Reichert, J. Nagy, W. Spevak, D. Charych, J. Am. Chem. Soc., 1995, 117, 829.

    CAS  Article  Google Scholar 

  34. 34.

    Y. Kyung, J. Hyun, G. Park, Biosens. Bioelectron., 2015, 15, 127.

    Google Scholar 

  35. 35.

    A. Sansee, A. Kamphan, R. Traiphol, F. Kielar, Colloids Surf. A, 2016, 497, 362.

    CAS  Article  Google Scholar 

  36. 36.

    R. Zairov, N. Shamsutdinova, S. Podyachev, S. Sudakova, G. Gimazetdinov, I. Rizvanov, V. Syakaev, V. Babaev, R. Amirov, A. Mustafina, Tetrahedron, 2016, 72, 2447.

    CAS  Article  Google Scholar 

  37. 37.

    S. N. Podyachev, S. N. Sudakova, G. Sh. Gimazetdinova, N. A. Shamsutdinova, V. V. Syakaev, T. A. Barsukova, N. Iki, D. V. Lapaev, A. R. Mustafina, New J. Chem., 2017, 41, 1526.

    CAS  Article  Google Scholar 

  38. 38.

    S. N. Podyachev, G. Sh. Gimazetdinov, S. N. Sudakova, N. A. Shamsutdinova, D. V. Lapaev, V. V. Syakaev, A. T. Gubaidullin, R. N. Nagimov, A. R. Mustafina, Tetrahedron, 73, 5397.

  39. 39.

    J.-C. G. Bünzli, Chem. Rev., 2010, 110, 2729.

    Article  Google Scholar 

Download references

Author information



Corresponding author

Correspondence to Yu. G. Elistratova.

Additional information

Dedicated to Academician of the Russian Academy of Sciences A. I. Konovalov on the occasion of his 85th birthday.

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 2, pp. 0394–0399, February, 2019.

Rights and permissions

Reprints and Permissions

About this article

Verify currency and authenticity via CrossMark

Cite this article

Elistratova, Y.G., Akhmadeev, B.S., Gimazetdinova, G.S. et al. Substrate-induced luminescence response of terbium-containing polymeric vesicles doped with the tetra- and bis-1,3-diketone derivatives of calix[4]arenes bearing nonyl substituents at the lower rims. Russ Chem Bull 68, 394–399 (2019).

Download citation

Key words

  • polydiacetylenic acid
  • terbium complexes
  • aggregation
  • luminescence
  • calix[4]-arenes
  • 1,3-diketones
  • mixed-ligand complexation