Abstract
A series of sorbents based on benzo-15-crown-5, various supports (styrene-divinylbenzene LPS-500, hydrophobized silica gel), and diluents (octan-1-ol, nitrobenzene, 1,1,7-trihydrododecafluoroheptanol (FHA), ionic liquid 1-butyl-3-methylimidazolium bis(trifluoromethylsulfonyl) imide (С4mim+Tf2N-)) and without diluents was obtained. The sorbents without diluents with the benzo-15-crown-5 content 20–30% have the maximum sorption characteristics (recovery of gold higher than 90%). The influence of the diluent and support nature, procedure of support pretreatment, impregnation time and temperature, and the solvent for impregnation on the sorption characteristics was studied. The maximum sorption characteristics were found for the sorbents based on the styrene-divinylbenzene support LPS-500. A high selectivity of the obtained sorbents toward gold was established, and the recovery of gold higher than 95% was achieved by the optimization of the synthesis procedure of the sorbents.
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S. Yu. Zaitsev, D. O. Solovyeva, I. S. Zaitsev, M. S. Tsarkova, Mendeleev Commun., 2016, 26, 40.
S. V. Nesterov, Russ. Chem. Rev., 2000, 69, 769.
N. A. Bezhin, I. I. Dovhyi, Russ. Chem. Rev., 2015, 84, 1279.
Ž. Grahek, S. Dulanská, G. Karanovic, I. Coha, I. Tucakovic, M. Nodilo, L. Mátel, J. Environ. Radioact., 2018, 181, 18.
R. M. Izatt, S. R. Izatt, N. E. Izatt, K. E. Krakowiak, R. L. Bruening, L. Navarro, Green Chem., 2015, 17, 2236.
S. R. Izatt, J. S. McKenzie, N. E. Izatt, R. L. Bruening, K. E. Krakowiak, R. M. Izatt, Molecular Recognition Technology: a Green Chemistry Process for Separation of Individual Rare Earth Metals, White Paper on Separation of Rare Earth Elements, American Fork, 2016, 12 pp.
V. V. Yakshin, O. M. Vilkova, N. A. Tsarenko, B. N. Laskorin, Dokl. Akad. Nauk, 1992, 323, 334 [Dokl. Chem. (Engl. Transl.), 1992].
V. V. Yakshin, O. M. Vilkova, N. A. Tsarenko, B. N. Laskorin, Dokl. Akad. Nauk, 1992, 324, 144 [Dokl. Chem. (Engl. Transl.), 1992].
V. V. Yakshin, O. M. Vilkova, N. A. Tsarenko, A. Yu. Tsivadze, Dokl. Chem., 2010, 430, 32.
V. V. Yakshin, O. M. Vilkova, S. M. Pluzhnik-Gladyr´, S. A. Kotlyar, Makrogeterotsikly [Macroheterocycles], 2010, 3, 114 (in Russian).
A. A. Vydysh, I. I. Dovhyi, A. Yu. Lyapunov, Uch. zap. Krym. feder. un-ta im. V. I. Vernadskogo. Ser. "Biologiya, khimiya" [Scientific Writings of the V. I. Vernadskii Crimea Federal University], 2015, 1, 197 (in Russian).
E. Ph. Horwitz, M. L. Dietz, R. Chiarizia, J. Radioanal. Nucl. Chem., 1992, 161, 575.
E. Ph. Horwitz, R. Chiarizia, M. L. Dietz, Solv. Extr. Ion Exch., 1992, 10, 313.
M. L. Dietz, J. Yaeger, L. R. Sajdak, Jr., M. P. Jensen, Sep. Sci. Technol., 2005, 40, 349.
E. Ph. Horwitz, M. L. Dietz, S. Rhoads, C. Felinto, N. H. Gale, J. Houghton, Anal. Chim. Acta, 1994, 292, 263.
J. J. Surman, J. M. Pates, H. Zhang, S. Happel, Talanta, 2014, 129, 623.
V. V. Yakshin, O. M. Vilkova, N. A. Tsarenko, A. Yu. Tsivadze, Dokl. Chem., 2010, 430, 54.
N. N. Popova, V. I. Zhilov, S. V. Demin, A. Yu. Tsivadze, V. V. Yakshin, O. M. Vilkova, Russ. J. Inorg. Chem., 2011, 56, 1128.
N. A. Bezhin, I. I. Dovhyi, A. Yu. Lyapunov, J. Radioanal. Nucl. Chem., 2015, 303, 1927.
N. A. Bezhin, I. I. Dovhyi, A. Yu. Lyapunov, J. Radioanal. Nucl. Chem., 2017, 311, 317.
V. V. Milutin, N. A. Nekrasova, I. I. Dovhyi, N. A. Bezhin, V. E. Baulin, A. Yu. Tsivadze, Radiochem., 2017, 59, 16622.
J. T. Chuang, J. G. Lo, J. Radioanal. Nucl. Chem., 1996, 204, 83.
R. Hanzel, P. Rajec, J. Radioanal. Nucl. Chem., 2000, 246, 607.
A. Zhang, Y. Z. Wei, M. Kumagai, T. Koyama, J. Radioanal. Nucl. Chem., 2004, 262, 739.
A. Zhang, Q. Hu, Zh. Chai, Sep. Sci. Technol., 2009, 44, 2146.
A. Zhang, Ch. Xiao, Y. Liu, Q. Hu, Ch. Chen, E. Kuraoka, J. Porous Mater., 2010, 17, 153.
M. L. Dietz, J. A. Dzielawa, I. Laszak, B. A. Young, M. P. Jensen, Green Chem., 2003, 5, 682.
J. L. Cortina, A. Warshawsky, Ion Exch. Solv. Extr., 1997, 13, 195.
A. V. Ananyev, N. A. Tsarenko, A. M. Strelnikova, A. M. Koshcheev, A. Yu. Tsivadze, Russ. Chem. Bull., 2014, 63, 1308.
V. S. Yankovskaya, I. I. Dovhyi, V. V. Milyutin, N. A. Nekrasova, N. A. Bezhin, A. Yu. Lyapunov, J. Radioanal. Nucl. Chem., 2017, 314, 119.
Novyi spravochnik khimika i tekhnologa. Osnovnye svoistva neorganicheskikh, organicheskikh i elementoorganicheskikh soedinenii [Chemist´s and Technologist´s New Reference Book. The Main Properties of Inorganic, Organic, and Organoelement Compounds], Eds N. K. Skvortsov, A. V. Moskvin, S. A. Simanov, and V. A. Stolyarov, NPO "Mir i Sem´ya," St. Petersburg, 2002, 1280 pp. (in Russian).
Novyi spravochnik khimika i tekhnologa. Obshchie svedeniya. Stroenie veshchestva. Fizicheskie svoistva vazhneishikh veshchestv. Aromaticheskie soedineniya. Khimiya fotograficheskikh protsessov. Nomenklatura organicheskikh soedinenii. Tekhnika laboratornykh rabot. Osnovy tekhnologii. Intellektual´naya sobstvennost´ [Chemist´s and Technologist´s New Reference Book. General Data. Matter Structure. Physical Properties of Most Important Substances. Aromatic Compounds. Chemistry of Photographic Processes. Nomenclature of Organic Compounds. Technology of Laboratory Works. Foundations of Technology. Intellec tual Ownership], Ed. A. V. Moskvin, NPO "Professional," St. Petersburg, 2006, 1464 pp. (in Russian).
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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 12, pp. 2275–2281, December, 2018.
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Vydysh, A.A., Dovhyi, I.I. & Bezhin, N.A. Impregnated type sorbents based on benzo-15-crown-5 for gold(III) extraction from hydrochloric solutions. Russ Chem Bull 67, 2275–2281 (2018). https://doi.org/10.1007/s11172-018-2370-6
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DOI: https://doi.org/10.1007/s11172-018-2370-6