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Synthesis and spectral luminescent properties of 4,4´,4´´,4´´´-tetra(tert-butyl)-5,5´,5´´,5´´´-tetrakis(phenylsulfanyl)phthalocyanines and their sulfo acids

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Abstract

Magnesium and zinc complexes of 4,4´,4´´,4´´´-tetra(tert-butyl)-5,5´,5´´,5´´´-tetra kis-(phenylsulfanyl)phthalocyanine were synthesized. The corresponding sulfo acids were prepared by sulfochlorination and further hydrolysis. Spectral luminescent properties of the synthesized phthalocyanine derivatives were studied. Introduction of sulfo groups resulted in a bathochromic shift of Q-band in the spectra recorded in DMF and pyridine regardless of the metal nature as well as in a hypsochromic shift in sulfuric acid.

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Correspondence to T. V. Tikhomirova.

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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 12, pp. 2201–2204, December, 2018.

Based on the materials of the VII International Conference on Physical Chemistry of Crown Compounds, Porphyrins, and Phthalocyanines (September 9–14, 2018, Tuapse, Russia).

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Tikhomirova, T.V., Znoyko, S.A., Petlina, A.I. et al. Synthesis and spectral luminescent properties of 4,4´,4´´,4´´´-tetra(tert-butyl)-5,5´,5´´,5´´´-tetrakis(phenylsulfanyl)phthalocyanines and their sulfo acids. Russ Chem Bull 67, 2201–2204 (2018). https://doi.org/10.1007/s11172-018-2356-4

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  • DOI: https://doi.org/10.1007/s11172-018-2356-4

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