Russian Chemical Bulletin

, Volume 67, Issue 10, pp 1878–1890 | Cite as

New benzo[f]quinolino[3,4-b][1,7]naphthyridine-6,8(5H,9H)-diones: synthesis, electronic, molecular, and crystal structures. Protonation and complexation with lanthanum and europium salts

  • N. A. UstynyukEmail author
  • H. V. Lavrov
  • D. N. Zarubin
  • F. M. Dolgushin
  • M. G. Ezernitskaya
  • I. P. Gloriozov
  • S. S. Zhokhov
  • N. I. Zhokhova
  • Yu. A. UstynyukEmail author


A series of novel benzo[f]quinolino[3,4-b][1,7]naphthyridine-6,8(5H,9H)-diones, which are promising ligands for the extractive separation of actinides and lanthanides, and also their complexes with lanthanum and europium were synthesized. The molecular and crystal structures of one among the ligands were determined by single crystal X-ray diffraction. The protonation of compounds was investigated by IR and NMR spectroscopy. The electronic structure of starting substances and protonated forms was estimated by DFT calculations.

Key words

pyridine-2,6-dicarboxylic acid dilactams intramolecular cross-coupling lanthanum europium DFT calculations single crystal X-ray diffraction 


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Copyright information

© Springer Science+Business Media, LLC, part of Springer Nature 2018

Authors and Affiliations

  • N. A. Ustynyuk
    • 1
    Email author
  • H. V. Lavrov
    • 1
  • D. N. Zarubin
    • 1
  • F. M. Dolgushin
    • 1
  • M. G. Ezernitskaya
    • 1
  • I. P. Gloriozov
    • 2
  • S. S. Zhokhov
    • 2
  • N. I. Zhokhova
    • 3
  • Yu. A. Ustynyuk
    • 2
    Email author
  1. 1.A. N. Nesmeyanov Institute of Organoelement CompoundsRussian Academy of SciencesMoscowRussian Federation
  2. 2.Department of ChemistryM. V. Lomonosov Moscow State UniversityMoscowRussian Federation
  3. 3.Department of PhysicsM. V. Lomonosov Moscow State UniversityMoscowRussian Federation

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