New benzo[f]quinolino[3,4-b][1,7]naphthyridine-6,8(5H,9H)-diones: synthesis, electronic, molecular, and crystal structures. Protonation and complexation with lanthanum and europium salts
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A series of novel benzo[f]quinolino[3,4-b][1,7]naphthyridine-6,8(5H,9H)-diones, which are promising ligands for the extractive separation of actinides and lanthanides, and also their complexes with lanthanum and europium were synthesized. The molecular and crystal structures of one among the ligands were determined by single crystal X-ray diffraction. The protonation of compounds was investigated by IR and NMR spectroscopy. The electronic structure of starting substances and protonated forms was estimated by DFT calculations.
Key wordspyridine-2,6-dicarboxylic acid dilactams intramolecular cross-coupling lanthanum europium DFT calculations single crystal X-ray diffraction
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- 5.M. Bubeníková, J. Rais, P. Selucký, J. Kvícala, J. Radiochim. Acta, 2013, 101,753.Google Scholar
- 8.M. Pojarova, M. Dusek, E. Makrlik, V. A. Babain, Acta Crystallogr., 2011, E67, o3197.Google Scholar
- 11.J. Y. Qi, Q. Y. Yang, R. H. Lam, Z. Y. Zhou, A. S. C. Chan, Acta Crystallogr., 2003, E59, o415–o416.Google Scholar
- 13.H. V. Lavrov, N. A. Ustynyuk, I. P. Gloriozov, Yu. A. Ustynyuk, M. Yu. Alyapyshev, L. I. Tkachenko, V. A. Babain, Tez. dokl. Mezhdunar. konf. po khimii heterotsiklicheskikh soedinenii "Kost-2015" [Intern. Conf. on Chemistry of Heterocyclic Compounds "Kost-2015", Abstrs] (October 8–15, 2015), Moscow, 2015, p.239.Google Scholar
- 14.H. Lavrov, N. Ustynyuk, I. Gloriozov, Yu. Ustynyuk, M. Alyapyshev, L. Tkachenko, V. Babain, Ninth Intern. Conf. on Nuclear and Radiochemistry, Abstrs (August 29–September 2, 2016), Helsinki, 2016, p.71.Google Scholar
- 22.APEX II Software Package, Bruker AXS Inc., 5465, East Cheryl Parkway, Madison, WI-53179, USA, 2005.Google Scholar
- 23.G. M. Sheldrick, Acta Crystallogr., 2015, C71, 3–8.Google Scholar