Abstract
Pentacoordinated monofluorosilanes R1SO2NHCHR2C(O)N(Me)CH2SiMe2F containing moieties of N′-methyl-N-(organosulfonyl)-2-amino acid amides of glycine, alanine, and leucine as C,O-chelating ligands were synthesized via the reaction of corresponding disiloxanes with BF3•Et2O. The structures of obtained compounds were investigated by single-crystal X-ray diffraction analysis.
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Based on the materials of the XIV International Conference "Spectroscopy of Coordination Compounds" (September 24–30, 2017, Tuapse, Russia) and the XXVII International Chugaev Conference on the Coordination Chemistry (October 2–6, 2017, Nizhny Novgorod, Russia).
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 7, pp. 1299–1306, July, 2018.
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Nikolin, A.A., Korlyukov, A.A., Kramarova, E.P. et al. Synthesis and structural features of new pentacoordinated monofluorosilanes containing C,O-chelate ligands based on 2-amino acid N-methylamides. Russ Chem Bull 67, 1299–1306 (2018). https://doi.org/10.1007/s11172-018-2215-3
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DOI: https://doi.org/10.1007/s11172-018-2215-3