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New ruthenocene-based ruthenium pincer complex bearing the C5Me4CF3 ligand

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Abstract

The first (trifluoromethyl)tetramethylruthenocene-based ruthenium pincer complex RuCl(CO)[{2,5-(Bu t2 PCH2)2C5H2}Ru(C5Me4CF3)] was synthesized by cyclometallation of the bisphosphine ligand {1,3-(Bu t2 PCH2)2C5H2}Ru(C5Me4CF3) with RuCl2(DMSO)4 in 2-methoxyethanol in the presence of NEt3. The new complex was fully characterized by 1H, 19F, 31P{1H}, 13C{1H} NMR and IR spectroscopy.

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation

    S. V. Safronov

  2. Institute of Organometallic Chemistry, I. Javakhishvili Tbilisi State University, 3 Chavchavadze Avenue, 0128, Tbilisi, Georgia

    A. A. Koridze

Authors
  1. S. V. Safronov
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  2. A. A. Koridze
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Correspondence to S. V. Safronov.

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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 7, pp. 1247–1250, July, 2018.

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Safronov, S.V., Koridze, A.A. New ruthenocene-based ruthenium pincer complex bearing the C5Me4CF3 ligand. Russ Chem Bull 67, 1247–1250 (2018). https://doi.org/10.1007/s11172-018-2208-2

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  • DOI: https://doi.org/10.1007/s11172-018-2208-2

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