Abstract
It is revealed by FTIR and electron absorption spectroscopy that the reactions of dimethyl sulfoxide with the nitro complexes of Co-porphyrins both in the solid phase and an inert solvent afford six-coordinate complexes with the general formula (DMSO)Со(Por)(NO2) (Por is meso-tetraphenyl- and meso-tetra-p-tolylporphyrinato dianions). These compounds are stable in the solid state, whereas they partially decompose in an inert solvent to form five- and six-coordinate complexes. The ambident nitrite and dimethyl sulfoxide ligands are coordinated to the metal atom through the N and O atoms, respectively, which was confirmed by the application of isotope-containing compounds 15NO2 and DMSO-d6.
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F. A. Cotton, G. Wilkinson, Advanced Inorganic Chemistry, Wiley, New York, 1988, 1281–1282.
Nitrosyl Complexes in Inorganic Chemistry, Biology and Medicine, Eds D. M. P. Mingos, Springer, Berlin, 2014, p.260.
P. C. Ford, Inorg. Chem., 2010, 49, 6226.
C. L. Dickinson, M. C. R. Symons, J. Phys. Chem., 1982, 86,917.
C. L. Dickinson, J. C. W. Chen, Biochemistry, 1975, 14, 3534.
J. A. Goodwin, R. Bailey, W. Pennington, Inorg. Chem., 2001, 40, 4217.
T. S. Kurtikyan, A. K. Mardyukov, J. A. Goodwin, Inorg. Chem., 2003, 42, 8489.
F. A. Walker, J. Am. Chem. Soc., 1970, 92, 4235.
W. Bhatti, M. Bhatti, P. Imbler, J. Pharm. Sci., 1972, 61,307.
A. Gordon, R. Ford, The Chemist’s Companion: A Handbook of Practical Data, Techniques, and References, 1973, 560 pp.
T. S. Kurtikyan, T. G. Stepanyan, A. V. Gasparyan, Koord. Khim., 1997, 23, 604 [Russ. J. Coord. Chem. (Engl. Transl.), 1997, 23] (in Russian).
T. S. Kurtikyan, A. V. Gasparyan, G. G. Martirosyan, G. A. Zhamkochyan, Zh. Prikl. Spektrosk., 1995, 62, 62 [J. Appl. Spectr. (Engl. Transl.), 1995, 62] (in Russian).
T. S. Kurtikyan, T. G. Stepanyan, Izv. Akad. Nauk, Ser. Khim., 1998, 716 [Russ. Chem. Bull. (Engl. Transl.), 1998, 47] (in Russian).
T. S. Kurtikyan, P. C. Ford, Angew. Chem., Int. Ed. Engl., 2006, 45,492.
K. S. Suslick, R. A. Watson, Inorg. Chem., 1991, 30,912.
K. Nakamoto, Infrared Spectra of Inorganic and Coordination Compounds, Wiley, New York, 1963.
T. G. Stepanyan, M. E. Akopyan, T. S. Kurtikyan, Koord. Khim., 2000, 26, 453 [Russ. J. Coord. Chem. (Engl. Transl.), 2000, 26] (in Russian).
J. A. Goodwin, T. S. Kurtikyan, B. Bin Jeng, Inorg. Chem., 2005, 44, 2215.
T. S. Kurtikyan, A. K. Mardyukov, J. A. Goodwin, Koord. Khim., 2008, 34, 613 [Russ. J. Coord. Chem. (Engl. Transl.), 2008, 34] (in Russian).
T. S. Kurtikyan, G. M. Gulyan, A. M. Dalaloyan, Inorg. Chem., 2010, 49, 7793.
B. S. Tovrog, S. E. Diamond, F. Mares, A. Szalkiewicz, J. Am. Chem. Soc., 1981, 103, 3522.
P. G. Jene, J. A. Ibers, Inorg. Chem., 2000, 39, 3823.
M. A. Andrews, T. C.-T. Chang, C.-W. F. Cheng, Organometallics, 1985, 4,268.
F. A. Cotton, R. Francis, J. Am. Chem. Soc., 1960, 82, 2986.
G. Sipos, E. E. Drinkel, R. Dorta, Chem. Soc. Rev., 2015, 44, 3834.
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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 7, pp. 1241–1246, July, 2018.
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Hovhannisyan, A.A., Minasyan, H.S., Kovalchukova, O.V. et al. Spectral study of the reactions of dimethyl sulfoxide with the nitrite complexes of Co-porphyrins. Russ Chem Bull 67, 1241–1246 (2018). https://doi.org/10.1007/s11172-018-2207-3
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DOI: https://doi.org/10.1007/s11172-018-2207-3