Skip to main content
SpringerLink
Log in

Synthesis, structure, and properties of Schiff base iodobismuthate and its alteration in DMSO solution

  • Published:
Russian Chemical Bulletin Aims and scope

Abstract

New hybrid iodobismuthates (C12H18N2)(BiI4)2 (1, C12H18N2 is N,N´-bis(1- methylethylidene)-1,4-benzоdiammonium dication) and (C6H4(NH3)2) [Bi2I8•2DMSO]•4DMSO (2, C6H4(NH3)2 is p-phenylenediammonium dication) were synthesized and their crystal structures were established. Compound 1 crystallizes in the space group P21/n, a = 7.632(4), b = 13.471(6), c = 14.556(5) Å, β = 93.57(4)°; compound 2 crystallizes in the space group P\(\overline 1 \) , a = 9.208(4), b = 12.203(5), c = 13.600(5) Å, α = 110.20(3)°, β = 97.28(4)°, γ = 110.04(4)°. In the crystal structure of compound 1, one-dimensional infinite BiI –4 polyanions are linked into a three-dimensional structure by N,N'-bis(1-methylethylidene)- 1,4-benzоdiammonium dications through N–H…I and C–H…I hydrogen bonds. Compound 1 is stable up to 200 °С, optical studies showed that it has a band gap of 2.15 eV. The recrystallization of compound 1 from DMSO is accompanied by the transformation of chain BiI –4 anions to binuclear [Bi2I8•2DMSO]2– anions, while the azomethine cation decomposes to form a p-phenylenediammonium dication.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. N. Mercier, N. Louvaina, W. Bi, CrystEngComm., 2009, 11,720.

    Article  CAS  Google Scholar 

  2. G. A. Fisher, N. C. Norman, Adv. Inorg. Chem., 1994, 41,233.

    Article  CAS  Google Scholar 

  3. O. Weber, K. Marshall, L. M. Dyson, M. T. Weller, Acta Crystallogr., Sect. B, 2015, 71,668.

    Article  CAS  Google Scholar 

  4. W. Bi, N. Leblanc, N. Mercier, P. Auban-Senzier, C. Pasquier, Chem. Mater., 2009, 21, 4099.

    Article  CAS  Google Scholar 

  5. J. Przeslawski, A. Piecha-Bisiorek, R. Jakubas, J. Mol. Struct., 2016, 1110,97.

    Article  CAS  Google Scholar 

  6. G. Xu, G.-C. Guo, M.-S. Wang, Z.-J. Zhang, W.-T. Chen, J.-S. Huang, Angew. Chem., Int. Ed. Engl., 2007, 46, 3249.

    Article  CAS  Google Scholar 

  7. N. Leblanc, M. Allain, N. Mercier, L. Sanguinet, Cryst. Growth Des., 2011, 11, 2064.

    Article  CAS  Google Scholar 

  8. S. Pandey, A. P. Andrews, A. Venugopal, Dalton Trans., 2016, 45, 8705.

    Article  CAS  PubMed  Google Scholar 

  9. A. M. Goforth, M. A. Tershansy, M. D. Smith, L. Peterson, Jr., J. G. Kelley, W. J. I. DeBenedetti, H.-C. Loye, J. Am. Chem. Soc., 2011, 133,603.

    Article  CAS  PubMed  Google Scholar 

  10. A. Gagor, M. Weclawik, B. Bondzior, R. Jakubas, CrystEngComm., 2015, 17, 3286.

    Article  CAS  Google Scholar 

  11. N. Elfaleh, S. Kamoun, J. Organomet. Chem., 2016, 819,95.

    Article  CAS  Google Scholar 

  12. S. A. Adonin, M. N. Sokolov, M. E. Rakhmanova, A. I. Smolentsev, I. V. Korolkov, S. G. Kozlova, V. P. Fedin, Inorg. Chem. Comm., 2015, 54,89.

    Article  CAS  Google Scholar 

  13. O. Toma, N. Mercier, C. Botta, J. Mater. Chem. C, 2016, 4, 5940.

    Article  CAS  Google Scholar 

  14. A. Kojima, K. Teshima, Y. Shirai, T. Miyasaka, J. Am. Chem. Soc., 2009, 131, 6050.

    Article  CAS  PubMed  Google Scholar 

  15. B. Saparov, D. B. Mitzi, Chem. Rev., 2016, 116, 4558.

    Article  CAS  PubMed  Google Scholar 

  16. S. S. Shin, J. P. C. Baena, R. C. Kurchin, A. Polizzotti, J. J. Yoo, S. Wieghold, M. G. Bawendi, T. Buonassisi, Chem. Mater., 2018, 30,336.

    Article  CAS  Google Scholar 

  17. T. Li, Y. Hu, C. A. Morrison, W. Wu, H. Hana, N. Robertson, Sustainable Energy Fuels, 2017, 1,308.

    Article  CAS  Google Scholar 

  18. M. Ruck, Angew. Chem., Int. Ed. Engl., 2001, 40, 1182.

    Article  CAS  Google Scholar 

  19. S. A. Adonin, M. N. Sokolov, V. P. Fedin, Coord. Chem. Rev., 2016, 312,1.

    Article  CAS  Google Scholar 

  20. S. A. Adonin, M. N. Sokolov, V. P. Fedin, Russ. J. Inorg. Chem., 2017, 62, 1789.

    Article  CAS  Google Scholar 

  21. M. A. Tershansy, A. M. Goforth, J. R. Gardinier, M. D. Smith, L. Peterson, Jr., H.-C. Loye, Solid State Sciences, 2007, 9,410.

    Article  CAS  Google Scholar 

  22. C. Hrizi, A. Samet, Y. Abid, S. Chaabouni, M. Fliyou, A. Koumina, J. Mol. Struct., 2011, 992,96.

    Article  CAS  Google Scholar 

  23. C. Hrizi, A. Trigui, Y. Abid, N. Chniba-Boudjada, P. Bordet, S. Chaabouni, J. Solid State Chem., 2011, 184, 3336.

    Article  CAS  Google Scholar 

  24. A. M. Goforth, L.-R. Peterson Jr., M. D. Smitha, H.-C. Loye, J. Solid State Chem., 2005, 178, 3529.

    Article  CAS  Google Scholar 

  25. W. Bi, N. Mercier, Chem. Commun., 2008, 5743.

    Google Scholar 

  26. N. A. Yelovik, A. V. Mironov, M. A. Bykov, A. N. Kuznetsov, A. V. Grigorieva, Z. Wei, E. V. Dikarev, A. V. Shevelkov, Inorg. Chem., 2016, 55, 4132.

    Article  CAS  PubMed  Google Scholar 

  27. M. C. Burla, M. Camalli, B. Carrozzini, G. Cascarano, C. Giacovazzo, G. Polidori, R. Spagna, J. Appl. Crystallogr., 2003, 36, 1103.

    Article  CAS  Google Scholar 

  28. V. Petricek, M. Dusek, L. Palatinus, Jana2000, Structure Determination Software Programs, Institute of Physics, Praha, 2000.

    Google Scholar 

  29. P. Kubelka, F. Munk, Z. Tech. Phys., 1931, 12,593.

    Google Scholar 

  30. P. Fedeli, F. Gazza, D. Calestani, P. Ferro, T. Besagni, A. Zappettini, G. Calestani, E. Marchi, P. Ceroni, R. Mosca, J. Phys. Chem. C, 2015, 119, 21304.

    Article  CAS  Google Scholar 

  31. E. H. Cordes, W. P. Jenkens, J. Am. Chem. Soc., 1962, 84,832.

    Article  CAS  Google Scholar 

  32. W. P. Jenks, Catalysis in Chemistry and Enzymology, New York, 1969, 656 p.

    Google Scholar 

  33. C. J. Carmalt, L. J. Farrugia, N. C. Norman, Z. Anorg. Allg. Chem., 1995, 621,47.

    Article  CAS  Google Scholar 

  34. C. Hrizi, N. Chaari, Y. Abid, N. Chniba-Boudjada, S. Chaabouni, Polyhedron, 2012, 46,41.

    Article  CAS  Google Scholar 

  35. A. J. Dennington, M. T. Weller, Dalton Trans., 2016, 45, 17974.

    Article  CAS  PubMed  Google Scholar 

  36. P. H. Svensson, L. Kloo, Chem. Rev., 2003, 103, 1649.

    Article  CAS  PubMed  Google Scholar 

  37. J. Laane, P. W. Jagodzinski, Inorg. Chem., 1980, 19,44.

    Article  CAS  Google Scholar 

  38. L. A. Kazitsyna, N. B. Kupletskaya, Primeneniye UF, IK, YAMR i mass-spektroskopii v organicheskoy khimii [Application of UV, IR, NMR Spectroscopy and Mass Spectrometry in Organic Chemistry], MGU Publ., Moscow, 1979, 240 pp. (in Russian).

    Google Scholar 

  39. M. S. Gruzdev, U. V. Chervonova, A. M. Kolker, N. E. Domracheva, Zh. Struktur. Khim., 2011, 52, 88 [Russ. Struct. Chem., 2011, 52].

    Google Scholar 

  40. V. Yu. Kotov, A. B. Ilyukhin, K. P. Birin, V. K. Laurinavichyute, A. A. Sadovnikov, Z. V. Dobrokhotova, S. A. Kozyukhin, New J. Chem., 2016, 40, 10041.

    Article  CAS  Google Scholar 

  41. N. A. Yelovik, T. A. Shestimerova, M. A. Bykov, J. Wei, E. V. Dikarev, A. V. Shevelkov, Russ. Chem. Bull., 2017, 66, 1196.

    Article  CAS  Google Scholar 

  42. V. V. Sharutin, I. V. Egorova, N. N. Klepikov, E. A. Boyarkina, O. K. Sharutina, Russ. J. Gen. Chem., 2008, 78, 1326.

    Article  CAS  Google Scholar 

  43. V. V. Sharutin, I. V. Egorova, N. N. Klepikov, E. A. Boyarkina, O. K. Sharutina, Russ. J. Inorg. Chem., 2009, 54,239.

    Article  Google Scholar 

  44. V. V. Sharutin, V. S. Senchurin, O. K. Sharutina, B. B. Kunkurdonova, T. P. Platonova, Russ. J. Inorg. Chem., 2011, 56, 1272.

    Article  CAS  Google Scholar 

  45. A. Weitze, A. Blaschette, D. Henschel, P. G. Jones, Z. Anorg. Allg. Chem., 1995, 621,229.

    Article  CAS  Google Scholar 

  46. R. P. Oertel, Spectrochim. Acta, Part A, 1970, 26,659.

    Article  CAS  Google Scholar 

  47. B. W. Skelton, P. C. Junk, A. H. White, Acta Crystallogr., 1996, 52,295.

    Article  Google Scholar 

  48. P. Nørby, M. R. V. Jørgensen, S. Johnsen, B. B. Iversen, Eur. J. Inorg. Chem., 2016, 1389.

    Google Scholar 

  49. A. B. Maurer, K. Hu, G. J. Meyer, J. Am. Chem. Soc., 2017, 139, 8066.

    Article  CAS  PubMed  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Chemistry, M. V. Lomonosov Moscow State University, Build. 3, 1 Leninskie Gory, 119991, Moscow, Russian Federation

    T. A. Shestimerova, N. A. Golubev, A. V. Mironov, M. A. Bykov & A. V. Shevelkov

Authors
  1. T. A. Shestimerova
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. N. A. Golubev
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. A. V. Mironov
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. M. A. Bykov
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. A. V. Shevelkov
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to T. A. Shestimerova.

Additional information

Based on the materials of the XXVII International Chugaev Conference on Coordination Chemistry (October 2–6, 2017, Nizhny Novgorod, Russia).

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 7, pp. 1212–1219, July, 2018.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Shestimerova, T.A., Golubev, N.A., Mironov, A.V. et al. Synthesis, structure, and properties of Schiff base iodobismuthate and its alteration in DMSO solution. Russ Chem Bull 67, 1212–1219 (2018). https://doi.org/10.1007/s11172-018-2204-6

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11172-018-2204-6

Key words

Search

Navigation