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Synthesis of water-soluble bis-N,O-chelate nickel(II) complexes based on new ligands – P-pyridyl-containing phospholane oxides

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Russian Chemical Bulletin Aims and scope

Abstract

A series of new N,O-hybrid ligands was synthesized by oxidation of pyridyl-substituted phospholanes. These ligands were employed in the first synthesis of water-soluble mononuclear nickel(II) complexes [NiL2(H2O)2](BF4)2 and [NiL2(MeCN)2](BF4)2. Physicochemical properties and crystalline structures of the synthesized compounds were thoroughly studied.

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Authors and Affiliations

  1. A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences, 8 ul. Arbuzova, 420088, Kazan, Russian Federation

    A. V. Shamsieva, K. R. Trigulova, R. R. Fayzullin, V. V. Khrizanforova, Yu. H. Budnikova, E. I. Musina & A. A. Karasik

Authors
  1. A. V. Shamsieva
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  2. K. R. Trigulova
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  3. R. R. Fayzullin
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  4. V. V. Khrizanforova
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  5. Yu. H. Budnikova
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  6. E. I. Musina
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  7. A. A. Karasik
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Corresponding author

Correspondence to A. V. Shamsieva.

Additional information

Based on the materials of the 27th International Chugaev Conference on Coordination Chemistry (October 2–6, 2017; Nizhny Novgorod, Russia).

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 7, pp. 1206–1211, July, 2018.

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Shamsieva, A.V., Trigulova, K.R., Fayzullin, R.R. et al. Synthesis of water-soluble bis-N,O-chelate nickel(II) complexes based on new ligands – P-pyridyl-containing phospholane oxides. Russ Chem Bull 67, 1206–1211 (2018). https://doi.org/10.1007/s11172-018-2203-7

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  • DOI: https://doi.org/10.1007/s11172-018-2203-7

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