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Role of macrocyclic effect in complex formation of palladium(II) with ligands anchored on a solid support

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Abstract

The method for grafting dithiacrown ether and its linear analogue to the silica surface using preliminary prepared organosilicon derivative is developed. The importance of the acylation step in the process of grafting is underlined. The acylation is required to prevent sorption of platinum metals complex anions by the anion exchange mechanism, the probability of which increases due to protonation of the spacer in an acidic medium. The interaction of palladium(II) with anchored ligands in hydrochloric acid media was studied in details. The comparative study of two sorbents revealed that the macrocyclic effect plays a negligible role in binding of palladi um(II) ions. Therefore, linear ligands are preferred for the development of sorbents for molecular recognition of platinum metals ions.

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Authors and Affiliations

  1. Moscow Techological University (M. V. Lomonosov Institute of Fine Chemical Technologies), 78 prosp. Vernadskogo, 119454, Moscow, Russian Federation

    T. M. Buslaeva & N. M. Bodnar

  2. Photochemistry Center of the Russian Academy of Sciences, 7A-1 ul. Novatorov, 119421, Moscow, Russian Federation

    S. P. Gromov

  3. Moscow Techological University (Institute of Physics and Technology), 78 prosp. Vernadskogo, 119454, Moscow, Russian Federation

    E. V. Kopylova

  4. Department of Chemistry, M. V. Lomonosov Moscow State University, Build. 3, 1 Leninskie Gory, 119991, Moscow, Russian Federation

    G. V. Lisichkin & H. V. Ehrlich

Authors
  1. T. M. Buslaeva
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  2. N. M. Bodnar
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  3. S. P. Gromov
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  4. E. V. Kopylova
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  5. G. V. Lisichkin
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  6. H. V. Ehrlich
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Correspondence to T. M. Buslaeva.

Additional information

Based on the materials of the XXVII International Chugaev Conference on Coordination Chemistry (October 2–6, 2017; Nizhny Novgorod, Russia).

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 7, pp. 1190–1195, July, 2018.

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Buslaeva, T.M., Bodnar, N.M., Gromov, S.P. et al. Role of macrocyclic effect in complex formation of palladium(II) with ligands anchored on a solid support. Russ Chem Bull 67, 1190–1195 (2018). https://doi.org/10.1007/s11172-018-2200-x

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  • DOI: https://doi.org/10.1007/s11172-018-2200-x

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