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9-Ethyl-3-{6-(het)aryl-[1,2,5]oxadiazolo[3,4-b]pyrazin-5-yl}-9H-carbazoles: synthesis and study of sensitivity to nitroaromatic compounds

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Abstract

5-(9-Ethyl-9H-carbazol-3-yl)-substituted 6-(het)aryl[1,2,5]oxadiazolo[3,4-b]pyrazines were synthesized by direct transition metal-free C—H functionalization in the pyrazine ring. Their photophysical and sensory properties with respect to nitrobenzene and 2,4-dinitrotoluene vapors were studied using a Nitroscan portable detector of nitro-explosive substances (Ekaterinburg, Russia).

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Authors and Affiliations

  1. I. Ya. Postovsky Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences, 22 ul. S. Kovalevskoi, 620219, Ekaterinburg, Russian Federation

    E. V. Verbitskiy, Yu. A. Kvashnin, G. L. Rusinov & V. N. Charushin

  2. Ural Federal University named after the first President of Russia B. N. Yeltsin, 19 ul. Mira, 620002, Ekaterinburg, Russian Federation

    E. V. Verbitskiy, A. A. Baranova, Yu. A. Yakovleva, K. О. Khokhlov, G. L. Rusinov & V. N. Charushin

Authors
  1. E. V. Verbitskiy
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  2. Yu. A. Kvashnin
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  3. A. A. Baranova
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  4. Yu. A. Yakovleva
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  5. K. О. Khokhlov
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  6. G. L. Rusinov
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  7. V. N. Charushin
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Corresponding author

Correspondence to E. V. Verbitskiy.

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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 6, pp. 1078–1082, June, 2018.

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Verbitskiy, E.V., Kvashnin, Y.A., Baranova, A.A. et al. 9-Ethyl-3-{6-(het)aryl-[1,2,5]oxadiazolo[3,4-b]pyrazin-5-yl}-9H-carbazoles: synthesis and study of sensitivity to nitroaromatic compounds. Russ Chem Bull 67, 1078–1082 (2018). https://doi.org/10.1007/s11172-018-2183-7

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  • DOI: https://doi.org/10.1007/s11172-018-2183-7

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