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Mechanochemical processes with the reaction-induced mechanical activation. Chemo-mechanochemical effect

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Abstract

The review addresses the special case of mechanical activation of solid-state chemical reactions when the stress field, strain, and defects in crystals are induced by the chemical reaction itself rather than by the external mechanical impact (chemo-mechanochemical (CMC) effect). This review presents the analysis and state-of-the-art of research activities in this area. Different cases of the CMC effect in homogeneous and heterogeneous systems are considered: with or without changes in the chemical composition, with or without formation of solid products, etc.

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  1. Institute of Solid-State Chemistry and Mechanochemistry, Siberian Branch of Russian Academy of Sciences, 18 ul. Kutateladze, 630128, Novosibirsk, Russian Federation

    V. V. Boldyrev

  2. Novosibirsk State University, 90 ul. Pirogova, 630090, Novosibirsk, Russian Federation

    V. V. Boldyrev

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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 6, pp. 0933–0948, June, 2018.

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Boldyrev, V.V. Mechanochemical processes with the reaction-induced mechanical activation. Chemo-mechanochemical effect. Russ Chem Bull 67, 933–948 (2018). https://doi.org/10.1007/s11172-018-2162-z

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