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Thermally initiated disproportionation of manganese(II) bis(1-hydroxyethylidene)diphosphonate. Formation and properties of the lepidoid structure of manganese(II) (1-hydroxyethylidene)diphosphonate-2-hydroxyethaneaminium whiskers. Agronomical efficiency of the manganese(II) complex with (1-hydroxyethylidene)diphosphonic acid

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Abstract

The reaction of poorly soluble manganese(II) bis(1-hydroxyethylidene)diphosphonate tetrahydrate (Mn(H3L)2•4H2O) with 2-aminoethanol (H2NCH2CH2OH) in an aqueous medium on heating to 70—80 оС causes the initial formation of soluble manganese(II) bis(1-hydroxyethylidene)diphosphonate tris(1-hydroxyethaneaminium) (Mn(H3L)2• •3H2NCH2CH2OH•4H2O), which then disproportionates to slightly soluble manganese(II) (1-hydroxyethylidene)diphosphonate-2-hydroxyethaneaminium (MnH2L•H2NCH2CH2OH) and coordination polymer of 1-hydroxyethylidenediphosphonic acid with 2-aminoethanol containing no metal cations. In the course of the reaction, MnH2L•H2NCH2CH2OH precipitates as whiskers that are grouped into a leaf (lepidoid) structure. The latter was examined by IR spectroscopy, X-ray phase analysis, scanning electron microscopy, atomic force microscopy, optical microscopy, and thermal desorption of nitrogen. The starting and resulting manganese compounds refer to poorly soluble crystalline complexes. The presence of a 2-aminoethanol molecule in the final product leads to an increase in the solubility from 0.40 to 0.54 g in 100 mL of the solution. Poorly soluble MnH2L•H2NCH2CH2OH is easily converted to a soluble form by the treatment with 2-aminoethanol or 2-amino-2-(hydroxy- methyl)propane-1,3-diol (H2NC(CH2OH)3). The agronomical efficiency of a solution of the Mn(H3L)2•3H2NCH2CH2OH•4H2O complex was studied on the cultures of white lupine Degas, spring wheat Ester, spring rape, and pea Stabil.

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Authors and Affiliations

  1. G. A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, 49 ul. Tropinina, 603950, Nizhny Novgorod, Russian Federation

    V. V. Semenov, N. V. Zolotareva, B. I. Petrov, O. V. Novikova & T. I. Kulikova

  2. N. I. Lobachevsky Nizhny Novgorod State University, 23 prosp. Gagarina, 603950, Nizhny Novgorod, Russian Federation

    O. V. Novikova & E. N. Razov

  3. Institute for Mechanical Engineering Problems, Russian Academy of Sciences, 85 ul. Belinskogo, 603024, Nizhny Novgorod, Russian Federation

    E. N. Razov

  4. Physical-Technical Research Institute, N. I. Lobachevsky Nizhny Novgorod State University, 23 prosp. Gagarina, 603950, Nizhny Novgorod, Russian Federation

    A. V. Kruglov & V. E. Kotomina

  5. Nizhny Novgorod State Agricultural Academy, 97 prosp. Gagarina, 603107, Nizhny Novgorod, Russian Federation

    E. Yu. Geiger, L. D. Varlamova & V. I. Titova

  6. Nizhny Novgorod Agricultural Research Institute, 38 p. Selektsionnaya stantsiya, 607686, Kstovsky District, Nizhny Novgorod Region, Russian Federation

    N. A. Korchenkina & A. P. Sakov

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  1. V. V. Semenov
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  2. N. V. Zolotareva
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  3. B. I. Petrov
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  8. V. E. Kotomina
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  9. E. Yu. Geiger
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  11. V. I. Titova
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  13. A. P. Sakov
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Correspondence to V. V. Semenov.

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Semenov, V.V., Zolotareva, N.V., Petrov, B.I. et al. Thermally initiated disproportionation of manganese(II) bis(1-hydroxyethylidene)diphosphonate. Formation and properties of the lepidoid structure of manganese(II) (1-hydroxyethylidene)diphosphonate-2-hydroxyethaneaminium whiskers. Agronomical efficiency of the manganese(II) complex with (1-hydroxyethylidene)diphosphonic acid. Russ Chem Bull 67, 336–344 (2018). https://doi.org/10.1007/s11172-018-2079-6

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  • DOI: https://doi.org/10.1007/s11172-018-2079-6

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