Russian Chemical Bulletin

, Volume 66, Issue 11, pp 2142–2144 | Cite as

Synthesis and molecular structure of a manganese tricarbonyl complex based on 5,6-nido-C2B8H12 carborane

  • A. I. Lazareva
  • I. V. Pisareva
  • E. V. Balagurova
  • A. F. Smolyakov
  • F. M. Dolgushin
  • I. A. Godovikov
  • I. T. Chizhevsky
Full Article


The anionic manganese tricarbonyl complex [1,1,1-(CO)3-isonido-1,2,4-MnC2B8H10]–was synthesized in the form of PPN and tmdaH salts (PPN is bis(triphenylphosphine)iminium, tmda is N,N,N’,N’-tetramethyl-1,8-diaminonaphthalene) by the reaction of the deprotonated form of the medium-size non-icosahedral carborane 5,6-nido-C2B8H12 with Mn(CO)5Br. The structure of the complex [tmdaH][1,1,1-(CO)3-isonido-1,2,4-MnC2B8H10] was deter-mined by X-ray diffraction.

Key words

manganese tricarbonyl complexes {C2B8}-carborane derivatives metalla-carboranes synthesis molecular structure 


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Copyright information

© Springer Science+Business Media, LLC, part of Springer Nature 2017

Authors and Affiliations

  • A. I. Lazareva
    • 1
  • I. V. Pisareva
    • 1
  • E. V. Balagurova
    • 1
  • A. F. Smolyakov
    • 1
    • 2
  • F. M. Dolgushin
    • 1
  • I. A. Godovikov
    • 1
  • I. T. Chizhevsky
    • 1
  1. 1.A. N. Nesmeyanov Institute of Organoelement CompoundsRussian Academy of SciencesMoscowRussian Federation
  2. 2.Faculty of Physics and Mathematics and Natural SciencesPeoples’ Friendship University of RussiaMoscowRussian Federation

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