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Russian Chemical Bulletin

, Volume 66, Issue 11, pp 2126–2130 | Cite as

Synthesis of N-substituted imidazo[4,5-e]benzo[1,2-c;3,4-c’]difuroxans

  • V. L. Korolev
  • V. V. Toporov
  • N. L. Merkulova
  • V. M. Danilenko
  • V. P. Ivshin
  • T. S. Pivina
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Abstract

N-Substituted imidazo[4,5-e]benzo[1,2-c;3,4-c’]difuroxans were synthesized by phase-transfer catalyzed alkylation of imidazo[4,5-e]benzo[1,2-c;3,4-c’]difuroxan salts with various alkylating agents. Acid hydrolysis of N-(ethoxycarbonylmethyl)imidazo[4,5-e]benzo-[1,2-c;3,4-c’]difuroxans gives the corresponding carboxylic acids. Structures of the synthesized compounds were confirmed by NMR spectroscopy, high resolution mass spectrometry, IR spectroscopy, and elemental anslysis.

Key words

imidazo[4,5-e]benzo[1,2-c;3,4-c’]difuroxans alkylation phase transfer catalysis hydrolysis 

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Copyright information

© Springer Science+Business Media, LLC, part of Springer Nature 2017

Authors and Affiliations

  • V. L. Korolev
    • 1
  • V. V. Toporov
    • 2
  • N. L. Merkulova
    • 1
  • V. M. Danilenko
    • 3
  • V. P. Ivshin
    • 2
  • T. S. Pivina
    • 1
  1. 1.N. D. Zelinsky Institute of Organic ChemistryRussian Academy of SciencesMoscowRussian Federation
  2. 2.Mari State UniversityYoshkar-OlaRussian Federation
  3. 3.Lyceum and Gymnasium Complex in the South-EastMoscowRussian Federation

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