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Russian Chemical Bulletin

, Volume 66, Issue 11, pp 2115–2121 | Cite as

Aluminosilicates with different pores structure in the synthesis of 2,2,4-trimethyl-1,2-dihydroquinoline and N-phenyl-2-propanimine

  • N. G. Grigor’eva
  • N. A. Filippova
  • A. R. Gataulin
  • S. V. Bubennov
  • M. R. Agliullin
  • B. I. Kutepov
  • Nama Narender
Full Article
  • 27 Downloads

Abstract

Physicochemical characteristics of microporous zeolites of various structural type (FAU, BEA, MTW), micro-meso-macroporous zeolite (H-Ymmm), and mesoporous aluminosilicate (ASM) were studied. Their catalytic activity in the reaction of aniline with acetone was examined. It was found that 2,2,4-trimethyl-1,2-dihydroquinoline was the main reaction product on the catalysts H-Ymmm and ASM (selectivity up to 68% at 100% conversion of aniline), while the reaction on zeolites with microporous structure mainly gave N-phenyl-2-propanimine (selectivity up to 91%).

Key words

dihydroquinolines imines zeolites hierarchical zeolites mesoporous aluminosilicates 

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Copyright information

© Springer Science+Business Media, LLC, part of Springer Nature 2017

Authors and Affiliations

  • N. G. Grigor’eva
    • 1
  • N. A. Filippova
    • 1
  • A. R. Gataulin
    • 1
  • S. V. Bubennov
    • 1
  • M. R. Agliullin
    • 1
  • B. I. Kutepov
    • 1
  • Nama Narender
    • 2
  1. 1.Institute of Petrochemistry and CatalysisRussian Academy of SciencesUfaRussian Federation
  2. 2.CSIR-Indian Institute of Chemical Technology Uppal RoadTarnaka, Hyderabad, Telangana StateIndia

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