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Russian Chemical Bulletin

, Volume 66, Issue 11, pp 2081–2089 | Cite as

Electronic structure of europium(iii) acrylate and methacrylate: an X-ray photoelectron spectroscopy and quantum chemical study

  • V. V. Korochentsev
  • E. V. Mikhailenko
  • A. V. Shurygin
  • V. I. Vovna
  • I. S. Os’mushko
  • A. G. Mirochnik
  • N. V. Petrochenkova
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Abstract

The electronic structure and specific features of the nature of chemical bonding in europium acrylate and europium methacrylate were investigated by X-ray photoelectron spectroscopy (XPS) and quantum chemistry methods. The effect of the replacement of acrylic acid by methacrylic acid was also studied. The assignment of bands in the valence region XPS spectra is proposed.

Key words

X-ray electron spectroscopy density functional theory carboxylates electronic structure rare-earth elements EuIII 

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Copyright information

© Springer Science+Business Media, LLC, part of Springer Nature 2017

Authors and Affiliations

  • V. V. Korochentsev
    • 1
  • E. V. Mikhailenko
    • 1
  • A. V. Shurygin
    • 1
  • V. I. Vovna
    • 1
  • I. S. Os’mushko
    • 1
  • A. G. Mirochnik
    • 2
  • N. V. Petrochenkova
    • 2
  1. 1.Far Eastern Federal UniversityVladivostokRussian Federation
  2. 2.Institute of ChemistryFar Eastern Branch of the Russian Academy of SciencesVladivostokRussian Federation

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