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Russian Chemical Bulletin

, Volume 66, Issue 6, pp 1066–1073 | Cite as

Optimization of the key steps of synthesis and study of the fundamental physicochemical properties of high energy compounds — 4-(2,2,2-trinitroethyl)-2,6,8,10,12-pentanitrohexaazaisowurtzitane and 4,10-bis(2,2,2-trinitroethyl)-2,6,8,12-tetranitrohexaazaisowurtzitane

  • O. A. Luk´yanovEmail author
  • N. I. Shlykova
  • G. V. Pokhvisneva
  • T. V. Ternikova
  • S. V. Nikitin
  • G. A. Smirnov
  • Yu. V. Nelubina
  • P. V. Dorovatovskii
  • T. S. Kon´kova
  • N. V. Murav´yov
  • A. N. Pivkina
Full Articles

Abstract

The key steps of the synthesis of two high energy compounds, namely, 4-(2,2,2-trinitroethyl)-2,6,8,10,12-pentanitrohexaazaisowurtzitane and 4,10-bis(2,2,2-trinitroethyl)-2,6,8,12-tetranitrohexaazaisowurtzitane, were optimized. Their enthalpy of formation, density, impact and friction sensitivity, and thermal stability were experimentally determined.

Key words

4-(2,2,2-trinitroethyl)-2,6,8,10,12-pentanitrohexaazaisowurtzitane 4,10-bis-(2,2,2-trinitroethyl)-2,6,8,12-tetranitrohexaazaisowurtzitane enthalpy of formation density impact and friction sensitivity thermal stability 

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Copyright information

© Springer Science+Business Media, LLC 2017

Authors and Affiliations

  • O. A. Luk´yanov
    • 1
    Email author
  • N. I. Shlykova
    • 1
  • G. V. Pokhvisneva
    • 1
  • T. V. Ternikova
    • 1
  • S. V. Nikitin
    • 1
  • G. A. Smirnov
    • 1
  • Yu. V. Nelubina
    • 2
  • P. V. Dorovatovskii
    • 3
  • T. S. Kon´kova
    • 4
  • N. V. Murav´yov
    • 4
  • A. N. Pivkina
    • 4
  1. 1.N. D. Zelinsky Institute of Organic ChemistryRussian Academy of SciencesMoscowRussian Federation
  2. 2.A. N. Nesmeyanov Institute of Organoelement CompoundsRussian Academy of SciencesMoscowRussian Federation
  3. 3.National Research Center “Kurchatov Institute”MoscowRussian Federation
  4. 4.N. N. Semenov Institute of Chemical PhysicsRussian Academy of SciencesMoscowRussian Federation

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