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Synthesis and structure of tris(4-fluorophenylantimony) dicarboxylates: (4-FC6H4)3Sb[OC(O)R]2, R = CH2I, C6F5

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Abstract

Tris(4-fluorophenyl)antimony reacts with iodoacetic and pentafluorobenzoic acids in the presence of tert-butylhydroperoxide to give tris(4-fluorophenyl)antimony bis(iodoacetate) and tris(4-fluorophenyl)antimony bis(pentafluorobenzoate), respectively. Structures of organoantimony compounds were established by 1H and 19F NMR spectroscopy and X-ray diffraction analysis.

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Authors and Affiliations

  1. South Ural State University (NRI), 76 prosp. Lenina, 454080, Chelyabinsk, Russian Federation

    V. V. Sharutin & O. K. Sharutina

Authors
  1. V. V. Sharutin
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  2. O. K. Sharutina
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Correspondence to V. V. Sharutin.

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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 4, pp. 0707—0710, April, 2017.

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Sharutin, V.V., Sharutina, O.K. Synthesis and structure of tris(4-fluorophenylantimony) dicarboxylates: (4-FC6H4)3Sb[OC(O)R]2, R = CH2I, C6F5 . Russ Chem Bull 66, 707–710 (2017). https://doi.org/10.1007/s11172-017-1796-6

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  • DOI: https://doi.org/10.1007/s11172-017-1796-6

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