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Oxidation of 2,3,6-trimethylphenol to 2,3,5-trimethyl-1,4-benzoquinon over binary xerogels TiO2—SiO2 in the three-phase system

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Abstract

The technique of synthesis of 2,3,5-trimethyl-1,4-benzoquinon via catalytic oxidation of 2,3,6-trimethylphenol in H2O2—H2O—PhCH3 system with vibrational stirring is developed. Xerogels TiO2 and TiO2—SiO2 were used as catalysts in the process. The effect of physicochemical properties of xerogels on the course and characteristics of oxidation is studied.

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Authors and Affiliations

  1. I. Ya. Postovsky Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences, 22/20 ul. S. Kovalevskoy, 620041, Ekaterinburg, Russian Federation

    Yu. V. Mikushina, A. B. Shishmakov & L. A. Petro

Authors
  1. Yu. V. Mikushina
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  2. A. B. Shishmakov
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  3. L. A. Petro
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Correspondence to Yu. V. Mikushina.

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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 4, pp. 0677—0682, April, 2017.

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Mikushina, Y.V., Shishmakov, A.B. & Petro, L.A. Oxidation of 2,3,6-trimethylphenol to 2,3,5-trimethyl-1,4-benzoquinon over binary xerogels TiO2—SiO2 in the three-phase system. Russ Chem Bull 66, 677–682 (2017). https://doi.org/10.1007/s11172-017-1791-y

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  • DOI: https://doi.org/10.1007/s11172-017-1791-y

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