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Germylenes and stannylenes based on aminobisphenolate ligands: insertion into the C—Br bond

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Abstract

A reaction of previously synthesized germylenes and stannylenes based on aminobisphenols RN{CH2[(5-R´)(3-But)C6H2(2-O—)]}2MII, M = Ge, R = CH2(2-Py), R´ = But (1); M = Ge, R = Et, R´ = Me (2); M = Sn, R = CH2(2-Py), R´ = But (3); M = Sn, R = Et, R´ = Me (4), containing (tetrylenes 1 and 3) or not containing (tetrylenes 2 and 4) a group capable of additional donation, with allyl bromide leads to the products of the insertion of tetrylenes into the C—Br bond: RN{CH2[(5-R´)(3-But)C6H2(2-O—)]}2M(Br)All, M = Ge, R = CH2(2-Py), R´ = But (5); M = Ge, R = Et, R´ = Me (6); M = Sn, R = CH2(2-Py), R´ = But (7); M = Sn, R = Et, R´ = Me (8). The structures of obtained derivatives were confirmed by NMR spectroscopy and elemental analysis. The structures of compounds 4, 5, and 7 were studied by X-ray crystallography. Stannylene 4 was found to be monomeric in the solid phase: the coordination number of the Sn atom is 3. The insertion products 5 and 7 are characterized by the coordination number 6 for the central atom.

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Authors and Affiliations

  1. N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991, Moscow, Russian Federation

    K. V. Zaitsev, E. A. Kuchuk, A. V. Churakov, G. S. Zaitseva, M. P. Egorov & S. S. Karlov

  2. Department of Chemistry, M. V. Lomonosov Moscow State University, Build. 3, 1 Leninskie Gory, 119991, Moscow, Russian Federation

    K. V. Zaitsev, E. A. Kuchuk, G. S. Zaitseva & S. S. Karlov

  3. N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31 Leninsky prosp., 119991, Moscow, Russian Federation

    A. V. Churakov

Authors
  1. K. V. Zaitsev
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  2. E. A. Kuchuk
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  3. A. V. Churakov
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  4. G. S. Zaitseva
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  5. M. P. Egorov
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  6. S. S. Karlov
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Correspondence to S. S. Karlov.

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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 4, pp. 0622—0627, April, 2017.

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Zaitsev, K.V., Kuchuk, E.A., Churakov, A.V. et al. Germylenes and stannylenes based on aminobisphenolate ligands: insertion into the C—Br bond. Russ Chem Bull 66, 622–627 (2017). https://doi.org/10.1007/s11172-017-1782-z

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  • DOI: https://doi.org/10.1007/s11172-017-1782-z

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