Abstract
The behavior of the thermodynamic functions for the adsorption system krypton—microporous carbon sorbent ACC is described. The dependences of the differential molar isosteric heat of adsorption, entropy, enthalpy, heat capacity, and differential molar energy of the adsorption system on the adsorption equilibrium parameters were studied over the temperature range from 178 to 393 K and at pressures ranging from 1 to 6•106 Pa. Consideration of the non-ideality of gas phase and non-inertness of the adsorbent leads to a temperature dependence of the thermodynamic functions of the studied adsorption system, especially in the range of high pressures of the adsorptive. The non-ideality of the gas phase and the energetics of the adsorbent—adsorbate system exert the most significant effect on the thermodynamic functions. The non-inertness of the adsorbent in the investigated range of parameters of the adsorption system has a weak effect on the thermodynamic functions of adsorption. In the region of high filling of ACC micropores, the entropy increases, indicating the existence of processes, which change the structure of the adsorbate in the micropores, in particular, to form associates.
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References
A. A. Fomkin, Adsorption, 2005, 11, 425.
G. A. Golovko, Kriogennoe proizvodstvo inertnykh gazov [Cryogenic Production of Inert Gases], Mashinostroenie, Moscow, 1983, 416 pp. (in Russian).
P. G. Menon, Chem. Rev., 1968, 68, 277.
R. M. Barrer, R. Papadopoulos, Pros. Roy. Soc. Lond., 1972, A326, 1566.
А. Czaplinski, O. W. Holda, Wiadomosci Chem., 1974, 28, 21.
P. Malbrunot, D. Vidal, J. Vermesse, R. Chahine, T. K. Bose, Langmuir, 1992, 8, 577.
B. P. Bering, I. I. Seliverstova, V. V. Serpinskii, A. A. Fomkin, Bull. Acad. Sci. USSR, Div. Chem. Sci., 1977, 26, 2606.
A. A. Fomkin, N. I. Regent, V. Yu. Gusev, S. G. Tkachenko, V. A. Eroshenko, V. V. Serpinskii, Bull. Acad. Sci. USSR, Div. Chem. Sci., 1989, 38, 1268.
B. Kuchta, L. Firlej, Mater. Sci., 2006, 26, 433.
F. R. Hung, K. E. Gubbins, Adsorption, 2007, 13, 425.
S. V. Potapov, A. A. Fomkin, V. A. Sinitsyn, A. V. Shkolin, Protect. Metals Phys. Chem. Surf., 2010, 46, 639.
V. Gusev, A. Fomkin, J. Coll. Interface Sci., 1994, 162, 279.
N. F. Fedorov, G. K. Ivanyuk, D. N. Gavrilov, V. V. Tetenov, G. N. Smetanin, V. V. Samonin, O. E. Babkin, Yu. A. Zaitsev, Uglerodnye adsorbenty i ikh primenenie v promyshlennosti (sb. statei) [Carbon Adsorbents and Their Use in Industry (Collection of Works)], Nauka, Moscow, 1983, p. 20 (in Russian).
S. I. Oreshkin, Titan i ego soedineniya [Titanium and Its Compounds], Izd. Akad. Nauk SSSR, Moscow, 1926, 111 pp. (in Russian).
R. N. Kyutt, E. A. Smorgonskaya, A. M. Danishevskii, S. K. Gordeev, A. V. Grechinskaya, Phys. Solid State, 1999, 41, 1359.
E. A. Smorgonskaya, R. N. Kyutt, S. K. Gordeev, A. V. Grechinskaya, A. M. Danishevskii, Phys. Solid State, 2000, 42, 1176.
M. M. Dubinin, Adsorbtsiya i poristost [Adsorption and Porosity]´, VAKhZ, Moscow, 1972, 127 pp. (in Russian).
TU-2114-004-39791733-2010, Kripton gazoobraznyi osoboi chistoty [Gaseous Krypton of Special Purity] (in Russian).
N. B. Vargaftik, Spravochnik po teplofizicheskim svoistvam gazov i zhidkostei [Reference Book on Thermophysical Properties of Gases and Liquids], Nauka, Moscow, 1972, 720 pp. (in Russian).
A. V. Shkolin, Ph. D. (Chem.) Thesis, Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Moscow, 2008, 263 pp. (in Russian).
A. A. Fomkin, A. V. Shkolin, I. E. Men´shchikov, A. L. Pulin, A. A. Pribylov, I. A. Smirnov, Measur. Techn., 2016, 58, 1387.
A. V. Shkolin, A. A. Fomkin, A. L. Pulin, V. Yu. Yakovlev, Instrum. Exp. Techn., 2008, 51, 150.
V. A. Bakaev, Bull. Acad. Sci. USSR, Div. Chem. Sci., 1971, 20, 2516.
V. A. Bakaev, Doct. Sci. (Chem.) Thesis, Institute of Physical Chemistry, Academy of Sciences of the USSR, Moscow, 1989, 348 pp. (in Russian).
F. T. Meehan, Proc. Roy. Soc., 1927, A115, 199.
A. V. Shkolin, A. A. Fomkin, Trudy VI Konf. molodykh uchenykh, aspirantov i studentov IFKhE RAN "Fizikokhimiya2011" [Proc. VI Conf. of Young Scientists, Post-Graduates, and Students of the Institute of Physical Chemistry and Electrochemistry of the Russian Academy of Sciences "Physicochemistry-2011"] (Moscow, November 1—30, 2010), Moscow, 2011, p. 35 (in Russian).
S. V. Potapov, A. V. Shkolin, A. A. Fomkin, Colloid. J., 2015, 76, 351.
L. Pauling, The Nature of the Chemical Bond and the Structure of Molecules and Crystals: An Introduction to Modern Structural Chemistry, Cornell Univ. Press, 1960, 644 pp.
A. I. Vlasov, V. A. Bakaev, M. M. Dubinin, V. V. Serpinskii, Dokl. Akad. Nauk SSSR, 1981, 260, 904 (in Russian).
V. V. Sychev, A. A. Vasserman, V. I. Nedostup, L. S. Veksler, Teplofizicheskie svoistva neona, argona, kriptona i ksenona [Thermophysical properties of Neon, Krypton, and Xenon], Izd. Standartov, Moscow, 1976, 636 pp. (in Russian).
A. A. Fomkin, N. I. Regent, V. V. Serpinskii, Bull. Acad. Sci. USSR, Div. Chem. Sci., 1989, 38, 1967.
L. G. Shehovtcova, A. A. Fomkin, Bull. Russ. Acad. Sci., Div. Chem. Sci., 1992, 41, 10.
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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 4, pp. 0607—0613, April, 2017.
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Shkolin, A.V., Fomkin, A.A. & Potapov, S.V. Thermodynamics of krypton adsorption on microporous carbon adsorbent at high pressures. Russ Chem Bull 66, 607–613 (2017). https://doi.org/10.1007/s11172-017-1780-1
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DOI: https://doi.org/10.1007/s11172-017-1780-1