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First coordination polymer based on diterpenoids. Synthesis, structure, and magnetic properties

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Abstract

One-dimensional coordination polymer was obtained by cation exchange reaction of triethylammonium salt of methyl ent-16α-H-phosphonyloxybeyeran-19-oate with CuCl2. Its structure was determined by single crystal X-ray diffraction analysis. The formation of hydrophilic channels consisting of phosphorus containing fragments, copper atoms, and water, which are framed by hydrophobic surroundings from tetracyclic bulky beyeran substituents, is observed in the crystal. The study of the temperature dependence of the static magnetic susceptibility of the polymer indicates a weak antiferromagnetic interaction between the copper spins.

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Authors and Affiliations

  1. A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences, 8 ul. Akad. Arbuzova, 420088, Kazan, Russian Federation

    O. N. Kataeva, V. L. Mamedova, K. A. Nikitina, K. E. Metlushka, O. G. Sinyashin & V. A. Alfonsov

  2. A. M. Butlerov Chemical Institute of Kazan (Volga Region) Federal University, 18 ul. Kremlevskaya, 420008, Kazan, Russian Federation

    K. A. Ivshin

  3. Institute for Solid and Materials Research, 20 Helmholtzstrasse, 01069, Dresden, Germany

    Yu. V. Krupskaya & V. E. Kataev

Authors
  1. O. N. Kataeva
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  2. V. L. Mamedova
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  3. K. A. Nikitina
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  4. K. E. Metlushka
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  5. K. A. Ivshin
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  6. Yu. V. Krupskaya
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  7. V. E. Kataev
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  8. O. G. Sinyashin
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  9. V. A. Alfonsov
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Corresponding author

Correspondence to V. A. Alfonsov.

Additional information

Dedicated to Academician of the Russian Academy of Sciences R. Z. Sagdeev on the occasion of his 75th birthday.

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 2, pp. 0362—0367, February, 2017.

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Kataeva, O.N., Mamedova, V.L., Nikitina, K.A. et al. First coordination polymer based on diterpenoids. Synthesis, structure, and magnetic properties. Russ Chem Bull 66, 362–367 (2017). https://doi.org/10.1007/s11172-017-1741-8

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  • DOI: https://doi.org/10.1007/s11172-017-1741-8

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