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Study of the reactivity of organonickel sigma-complexes towards nitriles

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Abstract

The reactivity of organonickel sigma-complexes of type [NiBr(Ar)(bpy)], where Ar = 2,6-dimethylphenyl (Xyl), 2,4,6-trimethylphenyl (Mes), 2,4,6-triisopropylphenyl (Tipp), 2,4,6-tricyclohexylphenyl (Tchp), bpy = 2,2´-bipyridine, towards nitriles (acetonitrile, propionitrile, chloroacetonitrile, benzonitrile) has been investigated. This reaction leads to imines by formation of new carbon—carbon bond between aromatic fragment and nitrile group C≡N.

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Authors and Affiliations

  1. A. E. Arbuzov Institute of Organic and Physical Chemistry, Russian Academy of Sciences, 8 ul. Akad. Arbuzova, 420088, Kazan, Russian Federation

    Z. N. Gafurov, I. F. Sakhapov, V. M. Babaev, A. B. Dobrynin, K. E. Metlushka, I. Kh. Rizvanov, G. R. Shaikhutdinova, O. G. Sinyashin & D. G. Yakhvarov

  2. A. M. Butlerov Institute of Chemistry, Kazan Federal University, 18 ul. Kremlyovskaya, 420008, Kazan, Russian Federation

    Z. N. Gafurov, I. F. Sakhapov & D. G. Yakhvarov

  3. Institute of Problems of Chemical Physics, Russian Academy of Sciences, 1 prosp. Akad. Semenova, 142432, Chernogolovka, Moscow region, Russian Federation

    V. A. Kurmaz

Authors
  1. Z. N. Gafurov
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  2. I. F. Sakhapov
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  3. V. M. Babaev
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  4. A. B. Dobrynin
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  5. V. A. Kurmaz
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  6. K. E. Metlushka
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  7. I. Kh. Rizvanov
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  8. G. R. Shaikhutdinova
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  9. O. G. Sinyashin
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  10. D. G. Yakhvarov
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Corresponding author

Correspondence to D. G. Yakhvarov.

Additional information

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 2, pp. 0254—0259, February, 2017.

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Gafurov, Z.N., Sakhapov, I.F., Babaev, V.M. et al. Study of the reactivity of organonickel sigma-complexes towards nitriles. Russ Chem Bull 66, 254–259 (2017). https://doi.org/10.1007/s11172-017-1725-8

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  • DOI: https://doi.org/10.1007/s11172-017-1725-8

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