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Cyclic acetals in the synthesis of polyoxamacrocycles

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Abstract

A selective one-pot procedure to access 8-, 9-, and 10-membered polyoxacycles bearing ester functions was elaborated. The procedure involved the copper-promoted reactions of cyclic acetals with ethyl 2-diazo-3-oxobutanoate to give the target compounds in yields up to 99%.

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Authors and Affiliations

  1. Ufa State Petroleum Technological University, 1 ul. Kosmonavtov, 450062, Ufa, Russian Federation

    G. N. Shaikhullina, R. M. Sultanova, G. Z. Raskil´dina & S. S. Zlotskii

  2. Ufa Institute of Chemistry, Russian Academy of Sciences, 71 prosp. Oktyabrya, 450054, Ufa, Russian Federation

    R. M. Sultanova & I. P. Baikova

Authors
  1. G. N. Shaikhullina
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  2. R. M. Sultanova
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  3. I. P. Baikova
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  4. G. Z. Raskil´dina
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  5. S. S. Zlotskii
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Corresponding author

Correspondence to R. M. Sultanova.

Additional information

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 1, pp. 0164—0167, January, 2017.

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Shaikhullina, G.N., Sultanova, R.M., Baikova, I.P. et al. Cyclic acetals in the synthesis of polyoxamacrocycles. Russ Chem Bull 66, 164–167 (2017). https://doi.org/10.1007/s11172-017-1715-x

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  • DOI: https://doi.org/10.1007/s11172-017-1715-x

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