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Photoprocesses in N-ammonioalkyl derivatives of azacrown-containing styryl dyes and their complexes with metal perchlorates

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Abstract

Photophysical processes and photochemical reactions in the N-ammonioalkyl derivatives of the azacrown-containing styryl dyes and their complexes with lead and barium perchlorates in MeCN and CH2Cl2 were studied by 1Н NMR spectroscopy, absorption spectroscopy, luminescence spectroscopy, laser kinetic spectroscopy, and quantum chemistry. Molecules of the styryl dyes and their complexes are able to undergo normal (fast) and delayed fluorescence and trans–cis-photoisomerization. The molecules in the triplet state participate in degradation processes of the electron excitation energy.

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Authors and Affiliations

  1. Center of Photochemistry, Russian Academy of Sciences, 7a ul. Novatorov, 119421, Moscow, Russian Federation

    L. S. Atabekyan, N. A. Lobova, A. I. Vedernikov, V. G. Avakyan, S. P. Gromov & A. K. Chibisov

  2. Department of Chemistry, M. V. Lomonosov Moscow State University, 1 Leninskie Gory, 119991, Moscow, Russian Federation

    S. P. Gromov

Authors
  1. L. S. Atabekyan
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  2. N. A. Lobova
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  3. A. I. Vedernikov
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  4. V. G. Avakyan
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  5. S. P. Gromov
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  6. A. K. Chibisov
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Corresponding author

Correspondence to S. P. Gromov.

Additional information

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 1, pp. 0047—0055, January, 2017.

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Atabekyan, L.S., Lobova, N.A., Vedernikov, A.I. et al. Photoprocesses in N-ammonioalkyl derivatives of azacrown-containing styryl dyes and their complexes with metal perchlorates. Russ Chem Bull 66, 47–55 (2017). https://doi.org/10.1007/s11172-017-1698-7

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  • DOI: https://doi.org/10.1007/s11172-017-1698-7

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