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Influence of molecular organization of an azido alcohol solution on the urethane formation kinetics

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Abstract

The quantitative data on the influence of molecular organization of CH2Cl2 solutions of diazidopropanol and its non-azide analog (isopropanol) and the concentrations of the alcohols and catalyst (dibutyltin dilaurinate) on the kinetics of urethane formation via the reaction with 1,6-hexamethylene diisocyanate were obtained. The series of reactivity were composed for various associates of hydroxyl groups of these alcohols in solutions in the catalytic and non-catalytic reactions.

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Authors and Affiliations

  1. Institute of Problems of Chemical Physics, Russian Academy of Sciences, 1 prosp. Akad. Semenova, 142432, Chernogolovka, Moscow Region, Russian Federation

    S. V. Karpov, V. P. Lodygina, G. V. Malkov & E. R. Badamshina

Authors
  1. S. V. Karpov
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  2. V. P. Lodygina
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  3. G. V. Malkov
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  4. E. R. Badamshina
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Correspondence to S. V. Karpov.

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To the 60th anniversary of the Institute of Problems of Chemical Physics, Russian Academy of Sciences.

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 10, pp. 2415—2420, October, 2016.

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Karpov, S.V., Lodygina, V.P., Malkov, G.V. et al. Influence of molecular organization of an azido alcohol solution on the urethane formation kinetics. Russ Chem Bull 65, 2415–2420 (2016). https://doi.org/10.1007/s11172-016-1599-1

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  • DOI: https://doi.org/10.1007/s11172-016-1599-1

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